A cis-dioxomolybdenum Schiff base complex: synthesis, crystal structure and catalytic activity in oxidation of olefins using hydrogen peroxide

被引：0
|
作者：
Nasim Tadayonpour
Saeed Rayati
Moayad Hossaini Sadr
Karim Zare
Andrzej Wojtczak
机构：
[1] Islamic Azad University,Department of Chemistry, Science and Research Branch
[2] K.N. Toosi University of Technology,Department of Chemistry
[3] N. Copernicus University,Faculty of Chemistry
来源：
Transition Metal Chemistry | 2015年 / 40卷
关键词：
Schiff Base; Schiff Base Ligand; Cyclooctene; Molybdenum Complex; Phenyl Methyl Siloxane;
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摘要：
A cis-dioxomolybdenum(VI) Schiff base complex [MoO2L] has been synthesized and structurally characterized. Homogeneous oxidation of olefins using the complex as a catalyst with hydrogen peroxide as oxidant in ethanol solution showed high catalytic activity for this complex. Under reflux conditions, the oxidation of cyclooctene, styrene, α-methyl styrene, 4-methyl styrene and 1-methyl cyclohexene with hydrogen peroxide gave the corresponding epoxides as the sole products.
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页码：891 / 897
页数：6
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