A cis-dioxomolybdenum Schiff base complex: synthesis, crystal structure and catalytic activity in oxidation of olefins using hydrogen peroxide

被引：0

作者：

Nasim Tadayonpour

Saeed Rayati

Moayad Hossaini Sadr

Karim Zare

Andrzej Wojtczak

机构：

[1] Islamic Azad University,Department of Chemistry, Science and Research Branch

[2] K.N. Toosi University of Technology,Department of Chemistry

[3] N. Copernicus University,Faculty of Chemistry

来源：

Transition Metal Chemistry | 2015年 / 40卷

关键词：

Schiff Base; Schiff Base Ligand; Cyclooctene; Molybdenum Complex; Phenyl Methyl Siloxane;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A cis-dioxomolybdenum(VI) Schiff base complex [MoO2L] has been synthesized and structurally characterized. Homogeneous oxidation of olefins using the complex as a catalyst with hydrogen peroxide as oxidant in ethanol solution showed high catalytic activity for this complex. Under reflux conditions, the oxidation of cyclooctene, styrene, α-methyl styrene, 4-methyl styrene and 1-methyl cyclohexene with hydrogen peroxide gave the corresponding epoxides as the sole products.

引用

页码：891 / 897

页数：6

共 50 条

[1] A cis-dioxomolybdenum Schiff base complex: synthesis, crystal structure and catalytic activity in oxidation of olefins using hydrogen peroxide
Tadayonpour, Nasim
Rayati, Saeed
Sadr, Moayad Hossaini
Zare, Karim
Wojtczak, Andrzej
TRANSITION METAL CHEMISTRY, 2015, 40 (08) : 891 - 897
[2] Cis-dioxomolybdenum(VI) complex bearing tridentate ONO isonicotinoyl hydrazone Schiff base: Synthesis, characterization, crystal structure, and catalytic activity investigation for the oxidation of sulfides
Kargar, Hadi
Fallah-Mehrjardi, Mehdi
Ashfaq, Muhammad
Munawar, Khurram Shahzad
Tahir, Muhammad Nawaz
JOURNAL OF MOLECULAR STRUCTURE, 2023, 1294
[3] Synthesis and crystal structure of cis-dioxomolybdenum(VI) complex with the Schiff base salicylaldehyde-2-pyrazinoylhydrazone
Syamal, A
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2004, 81 (09) : 803 - 803
[4] Synthesis of cis-Dioxomolybdenum(VI)-tridentate Schiff Base Complexes and Its Catalytic Activity on the Epoxidation of Soybean Oil
Zhang Shu-Yuan
Jiang Ping-Ping
Leng Yan
Xu Yu-Cheng
Mo Guan-Tian
Bian Gang
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2013, 34 (07): : 1703 - 1708
[5] Synthesis, Characterization and Biological Activity of Cis-Dioxomolybdenum(VI) Schiff base Complex [MoO2(L)2]
Liu, Qian
Yang, Yisi
Hao, Weidong
Xu, Zhihua
Zhu, Lihong
2013 INTERNATIONAL CONFERENCE ON AGRICULTURAL AND NATURAL RESOURCES ENGINEERING (ICANRE 2013), 2013, 5 : 178 - 183
[6] Ligand coordination sphere effect of Schiff base cis-dioxomolybdenum(VI) complexes in selective catalytic oxidation of alcohols
Liu, Haiwen
Zhuo, Zihan
Zhang, Yan
Wei, Hang
Zhang, Wenxin
Li, Tong
Mao, Zuodong
Wang, Weili
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2021, 53 (12) : 1253 - 1261
[7] Synthesis and crystal structure of cis-dioxomolybdenum(VI) complex with salicylaldehyde-2-pyrazinoylhydrazone
Sanyal, GS
Ganguly, R
Nath, PK
Butcher, RJ
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2002, 79 (06) : 486 - 488
[8] Bimetallic cis-dioxomolybdenum(VI) complex containing hydrazone ligand: Syntheses, crystal structure and catalytic studies
Kurbah, Sunshine Dominic
Kumar, Arvind
Syiemlieh, Ibanphylla
Asthana, M.
Lal, Ram A.
INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 86 : 39 - 43
[9] cis-Dioxo-molybdenum(VI) Schiff base complexes: Synthesis, crystal structure and catalytic performance for homogeneous oxidation of olefins
Rayati, Saeed
Rafiee, Nasim
Wojtczak, Andrzej
INORGANICA CHIMICA ACTA, 2012, 386 : 27 - 35
[10] Synthesis, characterization and crystal structure of a dioxomolybdenum(VI) complex with a N,O type bidentate Schiff base ligand as a catalyst for homogeneous oxidation of olefins
Bagherzadeh, Mojtaba
Latifi, Reza
Tahsini, Laleh
Amani, Vahid
Ellern, Arkady
Woo, L. Keith
POLYHEDRON, 2009, 28 (12) : 2517 - 2521

← 1 2 3 4 5 →