Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene

被引：0
|
作者：
D. B. Lempert
I. N. Zyuzin
A. V. Nabatova
A. I. Kazakov
L. S. Yanovskii
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Combustion, Explosion, and Shock Waves | 2019年 / 55卷
关键词：
1,4- diethynylbenzene; enthalpy of combustion; enthalpy of formation; solid fuel; ramjet engine; combustion temperature;
D O I：
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学科分类号：
摘要：
The standard enthalpy of formation of 1,4-diethynylbenzene experimentally to be 500.6 ± 6.7 kJ/mol. Calculations show that 1,4-diethynylbenzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-diethynylbenzene can be used as the basis to develop an effective dispersing agent of solid fuel that provides an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values provided by HMX and the other azides of N-heterocycles previously proposed for this purpose.
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页码：644 / 647
页数：3
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