Synthesis of ordered cerium-doped cubic mesoporous silica using long-chain ionic liquid as template

被引:0
|
作者
Yue H. [1 ]
Zhao H. [1 ]
Liu L. [1 ]
Wang S. [1 ]
Ruan Q. [1 ]
Wang T. [1 ]
机构
[1] Department of Chemistry, Yunnan Normal University
来源
关键词
Ce-MCM-48; Hydrothermal synthesis; Ionic liquid template; Mesoporous materials;
D O I
10.1007/s11705-008-0031-2
中图分类号
学科分类号
摘要
The long-chain ionic liquid 1-hexadecyl-3-methylimidazolium chloride (C16mimCl) was used as a template to prepare cerium-doped MCM-48 materials in basic medium by a hydrothermal synthesis procedure. The effect of the amount of Ce salt and C16mimCl/Si on the synthesis were discussed in detail. This mesoporous material exhibits a pore architecture which is cubic Ia3d gyroid and possesses a large surface area and a narrow pore distribution. Cerium in calcined porous framework exists in the form of well-dispersed tetrahedral coordination. The C16mimCl shows a high tendency toward self-aggregation that allows the formation of the cerium-doped gyroid mesostructure by using the appropriate amount of Ce salt. © Higher Education Press and Springer-Verlag GmbH 2008.
引用
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页码:135 / 139
页数:4
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