Reduction kinetics of neodymium chloride in the equimolar NaCl–KCl melt

被引：1
|
作者：
Chernova O.V. [1 ]
Zhukovin S.V. [1 ]
Bushuev A.N. [1 ]
机构：
[1] Vyatka State University, Kirov
来源：
Russian Metallurgy (Metally) | 2015年 / 2015卷 / 08期
关键词：
Rare earths;
D O I：
10.1134/S0036029515080042
中图分类号：
学科分类号：
摘要：
The kinetic parameters (transfer coefficients, heterogeneous constants of the charge transfer rate) of cathode reduction of the neodymium ion in the equimolar NaCl–KCl melt are determined by chronopotentiometry and chronovoltamperometry. The dependences of the kinetic parameters on temperature and the rare-earth metal chloride concentration are presented. A mechanism is proposed for the reduction of the NdCl6 3– complex in the equimolar NaCl–KCl melt. © 2015, Pleiades Publishing, Ltd.
引用
收藏
页码：619 / 625
页数：6
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