Luminescent mixed-ligand Eu(III) complexes with quinaldic acid and nitrogen-containing dimeric ligands are synthesized. The thermal and spectral-luminescent properties of the obtained mixedligand Eu(III) complexes are studied. It is shown that a water molecule and a neutral ligand are detached during thermolysis in two stages with endothermic effects. It is found that the quinaldinate ion is coordinated to a europium(III) ion in a bidentate fashion. The Stark structure of the 5D0–7Fj (j = 0, 1, 2) transitions in the low-temperature luminescence spectra of europium(III) complexes is analyzed.
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Institute of Chemistry, Far East Division, Russian Academy of Sciences, VladivostokInstitute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok
Polishchuk A.V.
Karaseva É.T.
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Institute of Chemistry, Far East Division, Russian Academy of Sciences, VladivostokInstitute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok
Karaseva É.T.
Pushilin M.A.
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Institute of Chemistry, Far East Division, Russian Academy of Sciences, VladivostokInstitute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok
Pushilin M.A.
Kaidalova T.A.
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Institute of Chemistry, Far East Division, Russian Academy of Sciences, VladivostokInstitute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok
Kaidalova T.A.
Karasev V.E.
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Institute of Chemistry, Far East Division, Russian Academy of Sciences, VladivostokInstitute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok