Synthesis and crystal structure of new alkali metal hydrogen tellurates

被引：0
|
作者：
A. V. Churakov
E. A. Ustinova
P. V. Prikhodchenko
T. A. Tripol’skaya
J. A. K. Howard
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic chemistry
[2] Durham University,Department of Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2007年 / 52卷
关键词：
Mother Liquor; Alkali Metal Atom; Telluric Acid; Equatorial Oxygen Atom; Colorless Needle Crystal;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New alkali metal hydrogen tellurates have been synthesized, and their structures have been determined by X-ray crystallography. Hydrogen tellurates I–VI contain centrosymmetric binuclear anions [Te2O10H4+x](4−x)−, where x=0, 1, 2. Hydrogen tellurates II and VI contain, in addition to the binuclear anion, mononuclear species [TeO6H4]2− and Te(OH)6, respectively. The CNs of alkali metals vary from 8 to 12. In all structures, the hydrogen atoms (of both the hydroxy groups and water molecules) are involved in hydrogen bonding.
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页码：1503 / 1510
页数：7
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