Electrochemical Properties of Nanocomposite Based on Polytriphenylamine Derivative and Single-Walled Carbon Nanotubes

被引:0
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作者
L. I. Tkachenko
G. V. Nikolaeva
A. G. Ryabenko
N. N. Dremova
I. K. Yakushchenko
E. I. Yudanova
O. N. Efimov
机构
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
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关键词
polytriphenylamine derivative; single-walled carbon nanotubes; nanocomposite; aprotic lithium electrolyte; electrochemistry;
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摘要
One-step synthesis of the stable dispersion of conjugated poly(4,4',4"-tris(N,N-diphenylamine) triphenylamine)—single-walled carbon nanotubes nanocomposite is carried out by the oxidative polymerization of the monomer of the triphenylamine derivative with a high density of free radicals of 4,4',4"- tris(N,N-diphenylamine)tripenylamine in the presence of the single-walled carbon nanotubes in concentrated formic acid. Benzoyl peroxide is used as an oxidant. Electroconductive film coatings are prepared by applying stable dispersion onto the Ni substrate. The coatings show a high specific electrochemical capacity and stability in long-term cycling in the aprotic 1 M LiClO4/propylene carbonate electrolyte.
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页码:1222 / 1232
页数:10
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