Homogeneous Catalytic Oxidation of Cyclohexene by Nitro Complexes of Copper(II)

被引：0
|
作者：
Pablo J. Baricelli
Alfredo Castillo
Clementina Longo
Alvaro J. Pardey
机构：
来源：
Reaction Kinetics and Catalysis Letters | 2000年 / 70卷
关键词：
Oxidation; copper complexes; cyclohexene; 1-hexene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
This work describes the preliminary study of the homogeneous oxidation reaction of cyclohexene by nitro complexes of copper(II), Cu(CH3CN)2(NO2)Cl (1) and Cu(CH3CN)2(NO2)2 (2) in acetonitrile, under oxygen pressure (20 atm) at 70 and 100°C. The results show the formation of 2-cyclohexen-1-one and 1,2-epoxyhexane-3-one as main reaction products. Also, it was observed that the oxidation reaction at 100°C with complexes 1 and 2 becomes more selective to the formation of 2-cyclohexene-1-one although the activity of both catalyst decreases.
引用
收藏
页码：133 / 138
页数：5
相关论文
共 50 条
  • [1] Homogeneous catalytic oxidation of cyclohexene by nitro complexes of copper(II)
    Baricelli, PJ
    Castillo, A
    Longo, C
    Pardey, AJ
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 2000, 70 (01): : 133 - 138
  • [2] Catalytic oxidation of 1-hexene and cyclohexene with molecular oxygen by iridium nitro complexes
    Baricelli, PJ
    Sánchez, VJ
    Pardey, AJ
    Moya, SA
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 164 (1-2) : 77 - 84
  • [3] Catalytic activity of nickel(II), copper(II) and oxovanadium(II)-dihydroindolone complexes towards homogeneous oxidation reactions
    Adam, Mohamed Shaker S.
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (04)
  • [4] Oxidation of cyclohexene and styrene catalysed by ruthenium(II) complexes under homogeneous conditions
    Kanmani, AS
    Vancheesan, S
    [J]. RECENT ADVANCES IN BASIC AND APPLIED ASPECTS OF INDUSTRIAL CATALYSIS, 1998, 113 : 285 - 292
  • [5] Homogeneous and heterogenized copper(II) complexes as catechol oxidation catalysts
    Louloudi, M
    Mitopoulou, K
    Evaggelou, E
    Deligiannakis, Y
    Hadjiliadis, N
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 198 (1-2) : 231 - 240
  • [6] Green, homogeneous oxidation of alcohols by dimeric copper(II) complexes
    Maurya, Abhishek
    Haldar, Chanchal
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2021, 74 (4-6) : 885 - 904
  • [7] Catalytic wet oxidation of thiocyanate with homogeneous copper(II) sulphate catalyst
    Collado, Sergio
    Laca, Adriana
    Diaz, Mario
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2010, 177 (1-3) : 183 - 189
  • [8] HOMOGENEOUS HYDROGENATION OF CYCLOHEXENE CATALYZED BY RUTHENIUM(II) COMPLEXES
    KHAN, MMT
    MOHIUDDIN, R
    VANCHEESAN, S
    SWAMY, B
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1981, 20 (06): : 564 - 566
  • [9] A catalytic process for the selective oxidation of alcohols by copper (II) complexes
    Ramakrishna, Dileep
    Bhat, Badekai Ramachandra
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (05) : 690 - 693
  • [10] STRUCTURE AND CATALYTIC PROPERTIES OF COMPLEXES OF COPPER WITH ANKB-2 AMPHOLYTE IN THE REACTION OF OXIDATION OF CYCLOHEXENE
    KOKORIN, AI
    BERENTSVEIG, VV
    [J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (08): : 1537 - 1540
12345