Catalytic oxidation of 1-hexene and cyclohexene with molecular oxygen by iridium nitro complexes

被引：17

作者：

Baricelli, PJ ^{[1
]}

Sánchez, VJ

Pardey, AJ

Moya, SA

机构：

[1] Univ Carabobo, Fac Ingn, Ctr Invest Quim, Valencia, Spain

[2] Univ Carabobo, Fac Expt Ciencias & Tecnol, Escuela Quim, Valencia, Spain

[3] Cent Univ Venezuela, Fac Ciencias, Escuela Quim, Caracas, Venezuela

[4] Univ Santiago Chile, Fac Quim & Biol, Dept Quim Aplicada, Santiago, Chile

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2000年 / 164卷 / 1-2期

关键词：

oxidation; iridium complexes; cyclohexene; 1-hexene; nitro complexes;

D O I：

10.1016/S1381-1169(00)00343-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH3CN)(4)NO2](A)(2) (A=PF6 (1) or BF4 (2)) has been studied in acetonitrile under P(O-2)=20 atm, T=120 degreesC, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1,2-epoxyhexane, 1-hexen-3-one, 2-hexenal, 1-hexen-3-ol and 2-hexen-l-ol and also oxidize cyclohexene to 2-cyclohexen-1-one, 7-oxabicyclo[4.1.0]hexane and 2-cyclohexen-l-ol. Preliminary kinetic parameters are reported for complex (1). (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：77 / 84

页数：8

共 50 条

[1] Catalytic oxidation of 1-hexene with molecular oxygen by iridium nitro complexes
L. A. Quijije
M. Mediavilla
A. J. Pardey
C. Longo de Pardey
P. Baricelli
S. A. Moya
[J]. Reaction Kinetics and Catalysis Letters, 1997, 62 : 251 - 256
[2] Catalytic oxidation of 1-hexene with molecular oxygen by iridium nitro complexes
Quijije, LA
Mediavilla, M
Pardey, AJ
de Pardey, CL
Baricelli, P
Moya, SA
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 1997, 62 (02): : 251 - 256
[3] HOMOGENEOUS-CATALYTIC ACETOXYLATION OF 1-HEXENE AND CYCLOHEXENE
TRUSHOVA, NV
DEVEKKI, AV
[J]. PETROLEUM CHEMISTRY, 1992, 32 (04) : 313 - 319
[4] CATALYTIC PROPERTIES OF IRIDIUM-TIN COMPLEXES IN THE HYDROGENATION OF CYCLOHEXENE AND HEXENE-1
BELOUSOV, VM
ANTONOV, PG
PALCHEVSKAYA, TA
[J]. TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA, 1994, 30 (01): : 55 - 60
[5] Promoted iridium complexes as catalysts in hydroformylation of 1-hexene
Moreno, MA
Haukka, M
Pakkanen, TA
[J]. JOURNAL OF CATALYSIS, 2003, 215 (02) : 326 - 331
[6] Homogeneous Catalytic Oxidation of Cyclohexene by Nitro Complexes of Copper(II)
Pablo J. Baricelli
Alfredo Castillo
Clementina Longo
Alvaro J. Pardey
[J]. Reaction Kinetics and Catalysis Letters, 2000, 70 : 133 - 138
[7] Unique solvent effect of microporous crystalline titanosilicates in the oxidation of 1-hexene and cyclohexene
Fan, Weibin
Wu, Peng
Tatsumi, Takashi
[J]. JOURNAL OF CATALYSIS, 2008, 256 (01) : 62 - 73
[8] Homogeneous catalytic oxidation of cyclohexene by nitro complexes of copper(II)
Baricelli, PJ
Castillo, A
Longo, C
Pardey, AJ
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 2000, 70 (01): : 133 - 138
[9] CATALYTIC ISOMERIZATION OF 1-HEXENE
HAY, RG
MONTGOMERY, CW
COULL, J
[J]. INDUSTRIAL AND ENGINEERING CHEMISTRY, 1945, 37 (04): : 335 - 339
[10] POLYMER BOUND TRANSITION METAL COMPLEXES FOR CATALYTIC OXIDATION OF CYCLOHEXENE WITH MOLECULAR OXYGEN
HAO Chengjun ZhAO Ganqing College of Chemistry and Chemical Engineering
[J]. Chinese Journal of Reactive Polymers, 2007, (Z1) : 66 - 71

← 1 2 3 4 5 →