Extraction of Uranium(VI) using D2EHPA/TOPO based supported liquid membrane

被引:0
|
作者
A. Kadous
M. A. Didi
D. Villemin
机构
[1] Tlemcen University,Department of Chemistry, Faculty of Sciences
[2] LCMT,ENSICAEN
关键词
Uranium; Extraction Time; D2EHPA; Extraction Yield; Polyvinylidene Difluoride;
D O I
暂无
中图分类号
学科分类号
摘要
This work concerns the extraction of U(VI) using supported liquid membrane (SLM) by di-(2-ethylhexyl) phosphoric acid (D2EHPA) and tri-n-octyl phosphine oxide (TOPO) with polyvinylidene difluoride (PVDF) as a membrane support. The influence of ionic strength (S), stirring rate (V) and extraction time (t) were studied. The effect of membrane thickness on the permeability and extraction yield of uranium was investigated. A comparative study was carried out using a 23 full factorial design between SLMs with one membrane and two membranes, and to achieve the best conditions of recovery procedure, obtaining the mutual interaction among variables and optimizing these variables. The recovery of U(VI) is almost quantitative, and the supported liquid membrane with two membranes in series is effective.
引用
收藏
页码:157 / 165
页数:8
相关论文
共 50 条
  • [21] PERMEATION RATES OF CADMIUM THROUGH A SUPPORTED LIQUID MEMBRANE CONTAINING D2EHPA
    TAKAHASHI, M
    OHTA, T
    NISHIGUCHI, M
    KATAYAMA, Y
    TAKEUCHI, H
    KAGAKU KOGAKU RONBUNSHU, 1988, 14 (04) : 549 - 552
  • [22] Intensification of Europium extraction through a supported liquid membrane using mixture of D2EHPA and Cyanex272 as carrier
    Zaheri, Parisa
    Abolghasemi, Hossein
    Maraghe, Mohammad Ghannadi
    Mohammadi, Toraj
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2015, 92 : 18 - 24
  • [23] Study on a novel flat renewal supported liquid membrane with D2EHPA and hydrogen nitrate for neodymium extraction
    Pei Liang
    Wang Liming
    Yu Guoqiang
    JOURNAL OF RARE EARTHS, 2012, 30 (01) : 63 - 68
  • [24] Liquid–liquid extraction of uranium from Egyptian phosphoric acid using a synergistic D2EHPA–DBBP mixture
    Ahmed A. Abdel-Khalek
    M. M. Ali
    A. E. M. Hussein
    A. F. Abdel-Magied
    Journal of Radioanalytical and Nuclear Chemistry, 2011, 288 : 1 - 7
  • [25] KINETICS OF THE MECHANISM OF EXTRACTION OF URANIUM(VI) FROM SULFURIC-ACID-SOLUTIONS OF D2EHPA
    BUROV, BI
    GOLYNKO, ZS
    SOVIET RADIOCHEMISTRY, 1989, 31 (06): : 685 - 692
  • [26] Recovery of Indium from LCD Waste by Solvent Extraction and the Supported Liquid Membrane with Strip Dispersion Using D2EHPA as the Extractant
    Yen, Feng-Chi
    Chang, Tien-Chin
    Laohaprapanon, Sawanya
    Chen, Yan-Ling
    You, Sheng-Jie
    SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2016, 23 : 63 - 73
  • [27] The uranium(VI) extraction mechanism of D2EHPA-TOPO from a wet process phosphoric acid
    Girgin, S
    Acarkan, N
    Sirkeci, AA
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2002, 251 (02) : 263 - 271
  • [28] Studies on the Recovery of Uranium from Phosphoric Acid Medium by D2EHPA/n-Dodecane Supported Liquid Membrane
    Singh, Suman Kumar
    Misra, S. K.
    Sudersanan, M.
    Dakshinamoorthy, A.
    SEPARATION SCIENCE AND TECHNOLOGY, 2009, 44 (01) : 169 - 189
  • [29] The uranium(VI) extraction mechanism of D2EHPA-TOPO from a wet process phosphoric acid
    S. Girgin
    N. Acarkan
    A. Ali Sirkeci
    Journal of Radioanalytical and Nuclear Chemistry, 2002, 251 : 263 - 271
  • [30] Facilitated transport of cationic dyes through a supported liquid membrane with D2EHPA as carrier
    Hajarabeevi, N.
    Bilal, I. Mohammed
    Easwaramoorthy, D.
    Palanivelu, K.
    DESALINATION, 2009, 245 (1-3) : 19 - 27