Synthesis and steric structure of N″-(arylmethylidene)-N″′-(1-methyl-3-phenylprop-2-yn-1-ylidene)thiocarbonohydrazides

被引：0
|
作者：
T. E. Glotova
M. Yu. Dvorko
N. N. Chipanina
A. I. Albanov
L. V. Sherstyannikova
O. N. Kazheva
A. N. Chekhlov
O. A. D’yachenko
机构：
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Division
[2] Russian Academy of Sciences,Institute of Chemical Physics Problems
来源：
Russian Journal of Organic Chemistry | 2008年 / 44卷
关键词：
Aromatic Aldehyde; Benzylidene; Compound IIIa; Aqueous Acetic Acid; Steric Structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Thiocarbonohydrazones derived from aromatic aldehydes reacted with 4-phenylbut-3-yn-2-one in aqueous acetic acid (20°C, 2 h) to produce previously unknown N″-[(E-s-cis)-arylmethylidene]-N″′-[(Z-s-trans)-1-methyl-3-phenylprop-2-yn-1-ylidene]thiocarbonohydrazides with high chemo-, regio-, and stereoselectivity. The steric structure of N″-[(E-s-cis)-benzylidene]-N″′-[(Z-s-trans)-1-methyl-3-phenylprop-2-yn-1-ylidene]thiocarbonohydrazide in crystal and in solution was studied by X-ray analysis and IR and NMR spectroscopy.
引用
收藏
页码：114 / 119
页数：5
相关论文
共 50 条
  • [41] N-Phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide
    de Oliveira, Adriano Bof
    Santos Feitosa, Barbara Regina
    Naether, Christian
    Jess, Inke
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 0205 - +
  • [42] Synthesis antimicrobial and anticancer activity of N′-arylmethylidene-piperazine-1-carbothiohydrazide
    Umasankar Kulandaivelu
    Boyapati Shireesha
    Chidara Mahesh
    Jannu Vincent Vidyasagar
    Tadikonda Rama Rao
    K. N. Jayaveera
    Philipp Saiko
    Geraldine Graser
    Thomas Szekeres
    Venkatesan Jayaprakash
    Medicinal Chemistry Research, 2013, 22 : 2802 - 2808
  • [43] Crystal structure of (Z)-2-(1-benzyl-2-oxoindolin-3-ylidene)-N-phenylhydrazine-1-carbothioamide
    Vimala, G.
    Haribabu, J.
    Karvembu, R.
    Kumar, B. V. N. Phani
    SubbiahPandi, A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O160 - +
  • [44] Crystal structure of methyl (E)-2-(1-methyl-2-oxoindolin-3-ylidene)acetate
    Savithri, M. P.
    Yuvaraj, P. S.
    Reddy, B. S. R.
    Raja, R.
    SubbiahPandi, A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O188 - +
  • [45] N-(Imidazolidin-2-ylidene)-1-arylmethanamine Oxides: Synthesis, Structure and Pharmacological Evaluation
    Saczewski, Jaroslaw
    Hudson, Alan
    Laird, Shayna
    Rybczynska, Apolonia
    Boblewski, Konrad
    Lehmann, Artur
    Ma, Daqing
    Maze, Mervyn
    Watts, Helena
    Gdaniec, Maria
    ARCHIV DER PHARMAZIE, 2012, 345 (01) : 33 - 42
  • [46] Synthesis and Structure Determination of 1-(4-Methoxyphenyl)-5-methyl-N′-(2-oxoindolin-3-ylidene)-1H-1,2,3-triazole-4-carbohydrazide
    Kariuki, Benson M.
    Abdel-Wahab, Bakr F.
    Farahat, Abdelbasset A.
    El-Hiti, Gamal A.
    MOLBANK, 2022, 2022 (02)
  • [47] STRUCTURE OF N2-PARA-BROMOPHENYL-N1-METHYL-N1-(PARA-TOLYL)ACETAMIDINE
    CISZAK, E
    GDANIEC, M
    KOSTURKIEWICZ, Z
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 1362 - 1364
  • [48] Synthesis and Structure of 5,5-Disubstituted N-[4-Methyl-3-phenylfuran-2(5H)-ylidene]-N′-phenylthioureas
    K. S. Avetisyan
    L. Kh. Galstyan
    R. A. Tamazyan
    A. G. Aivazyan
    Russian Journal of Organic Chemistry, 2018, 54 : 1109 - 1111
  • [49] Crystal Structure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
    R. A. C. Souza
    S. Guilardi
    M. M. M. Rubinger
    L. R. Terra
    E. C. Tavares
    J. A. Ellena
    Journal of Structural Chemistry, 2018, 59 : 1192 - 1194
  • [50] Synthesis and structure of (E)-N-(4-methoxyphenyl)-2-[4-(3-oxo-3-phenylprop-1-en-1-yl)phenoxy]acetamide
    Cong Nguyen Tien
    Trung Vu Quoc
    Dat Nguyen Dang
    Giang Le Duc
    Van Meervelt, Luc
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 184 - +
12345