Tris(1-adamantanecarboxylato)bismuth(III): Synthesis and structure

被引:0
|
作者
V. V. Sharutin
I. V. Egorova
O. K. Sharutina
L. A. Nevmeshkina
机构
[1] Blagoveshchensk State Pedagogical University,
来源
Russian Journal of Inorganic Chemistry | 2008年 / 53卷
关键词
Bismuth; Adamantyl; Carboxylate Ligand; Bismuth Atom; Triphenylbismuth;
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学科分类号
摘要
Tris(1-adamantanecarboxylato)bismuth(III) was synthesized by reacting triphenylbismuth with 1-adamantanecarboxylic acid in toluene. The bismuth atom in tetramer {Bi[OC(O)C10H15]3}4 is coordinated by 10 oxygen atoms of bidentate-chelating and two types of chelate-bridging adamantanecarboxylate ligands (Bi-O, 2.191–2.955 and 3.634 Å).
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页码:1733 / 1736
页数:3
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