Synthesis of novel 1,4-oxathiine derivatives containing polyfluoroalkyl substituents at positions 2 and 6

被引：0

作者：

Yaroslav S. Borodkin

Yuriy G. Shermolovich

机构：

[1] National Academy of Sciences of Ukraine,Institute of Organic Chemistry

来源：

Chemistry of Heterocyclic Compounds | 2021年 / 57卷

关键词：

1,4-dihydrooxathiines; enamines; 1,4-oxathianes; 1,4-oxathiines; sulfides; dehydrofluorination;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Dehydrofluorination of bis(1,1-dihydropolyfluoroalkyl) sulfides with lithium hydroxide in morpholine occurs in a controlled manner with the formation of a new type of bis(enamine) sulfides, bis[2-(morpholin-4-yl)polyfluoroalk-1-en-1-yl]sulfanes, hydrolysis and subsequent fluorination of which leads to the production of novel fluorine-containing 1,4-oxathiine derivatives with divalent sulfur.

引用

页码：69 / 74

页数：5

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