Synthesis of novel 1,4-oxathiine derivatives containing polyfluoroalkyl substituents at positions 2 and 6

被引：0
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作者：
Yaroslav S. Borodkin
Yuriy G. Shermolovich
机构：
[1] National Academy of Sciences of Ukraine,Institute of Organic Chemistry
来源：
Chemistry of Heterocyclic Compounds | 2021年 / 57卷
关键词：
1,4-dihydrooxathiines; enamines; 1,4-oxathianes; 1,4-oxathiines; sulfides; dehydrofluorination;
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学科分类号：
摘要：
Dehydrofluorination of bis(1,1-dihydropolyfluoroalkyl) sulfides with lithium hydroxide in morpholine occurs in a controlled manner with the formation of a new type of bis(enamine) sulfides, bis[2-(morpholin-4-yl)polyfluoroalk-1-en-1-yl]sulfanes, hydrolysis and subsequent fluorination of which leads to the production of novel fluorine-containing 1,4-oxathiine derivatives with divalent sulfur.
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页码：69 / 74
页数：5
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