Synthesis of nitrophenyl-substituted 1,3-thiazoline-2-thiones by oxirane ring opening with several dithiocarbamates

被引：0

作者：

I. V. Kulakov

A. M. Gazaliev

O. A. Nurkenov

D. M. Turdybekov

机构：

[1] Institute of Organic Synthesis and Coal Chemistry of Kazahstan Republic,

[2] International Scientific and Production Holding,undefined

[3] “Phytochemistry”,undefined

来源：

Chemistry of Heterocyclic Compounds | 2010年 / 46卷

关键词：

2-(4-nitrophenyl)oxirane; carbon disulfide; thiazole-2(3H)-thione; intramolecular heterocyclization; X-ray structural analysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Thiazolo-2(3H)-thiones have been prepared by the reaction of triethylamine dithiocarbamates and 4-nitrophenyloxirane via formation of intermediate 2-hydroxy-2-(4-nitrophenyl)ethyldithiocarbamates with simultaneous dehydrogenation of the thiazolidine ring to a thiazoline. It was found that both the basicity of the starting amines and the temperature influenced the course of the reaction.

引用

页码：490 / 494

页数：4

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