Iridium(IV) extraction with petroleum sulfoxides from hydrochloric acid solutions

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作者
N. G. Afzaletdinova
Yu. I. Murinov
机构
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center
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关键词
Iridium; Hydrochloric Acid Solution; Platinum Metal; Decanol; Phase Contact Time;
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摘要
Iridium(IV) extraction with petroleum sulfoxides (PSO) from hydrochloric acid solutions is studied. Optimum conditions of extraction are chosen. It is shown that in the investigated extraction systems for a phase contact time of 30 min, iridium(IV) is extracted by the ion-associative mechanism. Electronic, 1H NMR, and IR-spectroscopy, and elemental analysis are used to establish the structure of the extracted compound.
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页码:1312 / 1315
页数:3
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