2-(2-pyridyl)-3-thioindan-1-one: Synthesis, tautomerism, and complexing properties

被引:0
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作者
E. V. Sennikova
O. Yu. Korshunov
G. S. Borodkin
M. S. Korobov
V. G. Vlasenko
N. N. Kharabaev
A. D. Garnovskii
机构
[1] Southern Federal University,Research Institute of Physical and Organic Chemistry
[2] Research Institute of Physics,undefined
[3] Rostov State Building University,undefined
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关键词
EXAFS Spectrum; EXAFS Spectroscopy; Indandione; Coordination Core; EXAFS Function;
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摘要
Chelate and molecular complexes of 2-(2-pyridyl)-3-thioindan-1-one were prepared. The structure of the ligand (prevalent tautomeric form), including the coordination mode, was proved by 1H NMR, IR, and EXAFS spectroscopy and by quantum-chemical calculations. The soft-hard properties of the ligand were demonstrated.
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页码:1802 / 1806
页数:4
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