Reaction of Polyhalo Semiquinoid Structures Originating from 4-Aroyl(arylsulfonyl)oximino-2,5-cyclohexadiene-1-ones with Arylsulfinic Acids

被引：0
|
作者：
A.P. Avdeenko
S.A. Zhukova
机构：
[1] Donbass State Machinebuilding Academy,
来源：
Russian Journal of Organic Chemistry | 2001年 / 37卷
关键词：
Alcohol; Organic Chemistry; Chlorine; Phosphite; Nucleophilic Substitution;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Stable semiquinoid structures, 4-aroyl(arylsulfonyl)oximino-2,6-dimethyl-5,6-dichloro-2-cyclohexen-1-ones, do not react with dialkyl phosphites, alcohols, tosylhydrazine, p-toluidine, and hydrazoic acid. In reactions with arylsulfinic acids occurs a nucleophilic substitution of chlorine at the sp3-hybridized C5 carbon in the minor Z-isomer yielding 4-aroyl(arylsulfonyl)oximino-5-arylsulfonyl-2,6-dimethyl-6-chloro-2-cyclohexen-1-ones.
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页码：281 / 283
页数：2
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    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 37 (02) : 281 - 283
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    [J]. Russian Journal of Organic Chemistry, 2008, 44 : 542 - 552
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    Avdeenko, A. P.
    Pirozhenko, V. V.
    Shishkin, O. V.
    Shishkina, S. V.
    Konovalova, S. A.
    Ludchenko, O. N.
    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 44 (04) : 542 - 552
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