Effects of base metal promoters in VOC catalysts for chlorocarbons and n-Hexane Oxidation

被引:0
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作者
Bo-Hyuk Jang
Sung-Sik Lee
Tae-Hun Yeon
Jae-Eui Yie
机构
[1] R&D Center,Heesung Engelhard Corp.
[2] Ajou University,School of Chem. Eng.
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Chlorocarbons; n-Hexanem; VOC Oxidation; Chromium; Promoters;
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摘要
The oxidation reactions of dichloromethane, dichloroethane and n-hexane were carried out over honey-comb type platinum basic VOC catalyst (BVC) containing vanadium, chromium, manganese, cobalt, copper or barium. In dichloromethane and dichloroethane catalytic oxidation up to 450 °C, chromium was found as the most active component. Although vanadium was also effective initially, it was deactivated after treatment in the furnace at 800 °C for 120 hours. Chromium, cobalt, vanadium and barium promoted catalysts showed higher activities than BVC in the reaction of n-hexane.
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页码:516 / 521
页数:5
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