Crystal and molecular structure of [Au(C14H24N4)][H3O](ClO4)4

被引：0
|
作者：
V. A. Afanasyeva
L. A. Glinskaya
R. F. Klevtsova
L. A. Sheludyakova
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
来源：
Journal of Structural Chemistry | 2005年 / 46卷
关键词：
gold(III); tetraazamacrocyclic complex; doubly protonated; tetrimine; crystal and molecular structure; IR spectra;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The crystal and molecular structure of doubly protonated tetraazamacrocyclic complex of gold(III) [Au(C14H24N4)][H3O](ClO4)4 has been determined. The crystals are monoclinic: a = 11.158(2) Å, b = 8.243(1) Å, c = 14.756(2) Å; β = 98.65(1)°, V = 1341.8(3) Å3, Z = 2, ρ(calc) = 1.134 g/cm3, space group P21/n. The structure is built of almost flat centrosymmetrical Au(C14H24N4)]3+ and [H3O]+ cations and [ClO4]− anions. The gold atom is coordinated with four nitrogen atoms of the ligand forming a flat square. The coordinated ligand is protonated at its γ-carbon atoms of the two six-membered chelate rings. The Au-N bond lengths are almost identical (the mean value is 1.994 Å). The six-membered rings of the complex contain C=N diimine bonds. The [H3O]+ oxonium ion has H-bonds with the oxygen atoms of perchlorate ions.
引用
收藏
页码：131 / 136
页数：5
相关论文
共 50 条
  • [1] Crystal and molecular structure of [Au(C14H24N4)][H3O](ClO4)4
    Afanasyeva, VA
    Glinskaya, LA
    Klevtsova, RF
    Sheludyakova, LA
    JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (01) : 131 - 136
  • [2] Introduction of halogen atoms into gold(III) tetraaza metallocomplexes.: Crystal and molecular structure of [Au(C9H18N4Br)](ClO4)2 and [Au(C14H20N4Br2)]ClO4
    Afanasieva, V. A.
    Glinskaya, L. A.
    Klevtsova, R. F.
    Mironov, I. V.
    Sheludyakova, L. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 48 (02) : 289 - 299
  • [3] Introduction of halogen atoms into gold(III) tetraaza metallocomplexes. Crystal and molecular structure of [Au(C9H18N4Br)](ClO4)2 and [Au(C14H20N4Br2)]ClO4
    V. A. Afanasieva
    L. A. Glinskaya
    R. F. Klevtsova
    I. V. Mironov
    L. A. Sheludyakova
    Journal of Structural Chemistry, 2007, 48 : 289 - 299
  • [4] Crystal structure of N,N′-diphenylguanidinium perchlorate, (C13H14N3)(ClO4)
    Paixao, JA
    Silva, PSP
    Beja, AM
    Silva, MR
    da Veiga, LA
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1998, 213 (02): : 419 - 420
  • [5] Synthesis and Properties of C8H24N4（ClO4）4 and C8H24N4（NO3）4∙2H2O
    Liu, Wei
    Gou, Xiao-Dong
    Guo, Xiao-Zhuang
    Yang, Cai
    Hanneng Cailiao/Chinese Journal of Energetic Materials, 2024, 32 (11): : 1138 - 1144
  • [6] Investigation of protonation of the tetraazamacrocyclic complex of gold(III) [Au(C14H22N4)]+ in water.: Synthesis and crystal and molecular structures of [Au(C14H23N4)](ClO4)2
    Afanasieva, VA
    Mironov, IV
    Glinskaya, LA
    Klevtsova, RF
    Sheludyakova, LA
    JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 45 (06) : 1014 - 1021
  • [7] Investigation of Protonation of the Tetraazamacrocyclic Complex of Gold(III) [Au(C14H22N4)]+ in Water. Synthesis and Crystal and Molecular Structures of [Au(C14H23N4)](ClO4)2
    V. A. Afanasieva
    I. V. Mironov
    L. A. Glinskaya
    R. F. Klevtsova
    L. A. Sheludyakova
    Journal of Structural Chemistry, 2004, 45 : 1014 - 1021
  • [8] The Crystal Structure of Indium Perchlorates [In(H2O)6](ClO4)3 and [In(H2O)6](ClO4)3 • 3H2O
    Ilyukhin, A. B.
    Malyarik, M. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (04) : 476 - 479
  • [9] Crystal structure of diethylenetriaminesilver(I) perchlorate, Ag(C4H13N3)(ClO4)
    Zhu, HL
    Shao, SC
    Ma, JL
    Qiu, XY
    Yang, S
    Sun, L
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2003, 218 (04): : 499 - 500
  • [10] C8H24N4（ClO4）4和C8H24N4（NO3）4·2H2O的合成与性能
    刘威
    苟晓东
    郭晓壮
    杨彩
    含能材料, 2024, 32 (11) : 1138 - 1144
12345