Crystal and molecular structure of [Au(C14H24N4)][H3O](ClO4)4

被引：3

作者：

Afanasyeva, VA ^{[1
]}

Glinskaya, LA ^{[1
]}

Klevtsova, RF ^{[1
]}

Sheludyakova, LA ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 46卷 / 01期

关键词：

gold(III); tetraazamacrocyclic complex; doubly protonated; tetrimine; crystal and molecular structure; IR spectra;

D O I：

10.1007/s10947-006-0019-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of doubly protonated tetraazamacrocyclic complex of gold(III) [Au(C14H24N4)][H3O](ClO4)(4) has been determined. The crystals are monoclinic: a=11.158(2) angstrom, b=8.243(1)angstrom, c=14.756(2) angstrom; beta=98.65(1)degrees, V=1341.8(3)angstrom(3), Z=2, rho(calc)=1.134 g/cm(3), space group P2(1)/n. The structure is built of almost flat centrosymmetrical Au(C14H24N4)](3+) and [H3O](+) cations and [ClO4](-) anions. The gold atom is coordinated with four nitrogen atoms of the ligand forming a flat square. The coordinated ligand is protonated at its gamma-carbon atoms of the two six-membered chelate rings. The Au-N bond lengths are almost identical (the mean value is 1.994 angstrom). The six-membered rings of the complex contain C=N diimine bonds. The [H3O](+), oxonium ion has H-bonds with the oxygen atoms of perchlorate ions.

引用

页码：131 / 136

页数：6

共 50 条

[1] Crystal and molecular structure of [Au(C14H24N4)][H3O](ClO4)4
V. A. Afanasyeva
L. A. Glinskaya
R. F. Klevtsova
L. A. Sheludyakova
Journal of Structural Chemistry, 2005, 46 : 131 - 136
[2] Introduction of halogen atoms into gold(III) tetraaza metallocomplexes.: Crystal and molecular structure of [Au(C9H18N4Br)](ClO4)2 and [Au(C14H20N4Br2)]ClO4
Afanasieva, V. A.
Glinskaya, L. A.
Klevtsova, R. F.
Mironov, I. V.
Sheludyakova, L. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 48 (02) : 289 - 299
[3] Introduction of halogen atoms into gold(III) tetraaza metallocomplexes. Crystal and molecular structure of [Au(C9H18N4Br)](ClO4)2 and [Au(C14H20N4Br2)]ClO4
V. A. Afanasieva
L. A. Glinskaya
R. F. Klevtsova
I. V. Mironov
L. A. Sheludyakova
Journal of Structural Chemistry, 2007, 48 : 289 - 299
[4] Crystal structure of N,N′-diphenylguanidinium perchlorate, (C13H14N3)(ClO4)
Paixao, JA
Silva, PSP
Beja, AM
Silva, MR
da Veiga, LA
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1998, 213 (02): : 419 - 420
[5] Synthesis and Properties of C8H24N4（ClO4）4 and C8H24N4（NO3）4∙2H2O
Liu, Wei
Gou, Xiao-Dong
Guo, Xiao-Zhuang
Yang, Cai
Hanneng Cailiao/Chinese Journal of Energetic Materials, 2024, 32 (11): : 1138 - 1144
[6] Investigation of protonation of the tetraazamacrocyclic complex of gold(III) [Au(C14H22N4)]+ in water.: Synthesis and crystal and molecular structures of [Au(C14H23N4)](ClO4)2
Afanasieva, VA
Mironov, IV
Glinskaya, LA
Klevtsova, RF
Sheludyakova, LA
JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 45 (06) : 1014 - 1021
[7] Investigation of Protonation of the Tetraazamacrocyclic Complex of Gold(III) [Au(C14H22N4)]+ in Water. Synthesis and Crystal and Molecular Structures of [Au(C14H23N4)](ClO4)2
V. A. Afanasieva
I. V. Mironov
L. A. Glinskaya
R. F. Klevtsova
L. A. Sheludyakova
Journal of Structural Chemistry, 2004, 45 : 1014 - 1021
[8] The Crystal Structure of Indium Perchlorates [In(H2O)6](ClO4)3 and [In(H2O)6](ClO4)3 • 3H2O
Ilyukhin, A. B.
Malyarik, M. A.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (04) : 476 - 479
[9] Crystal structure of diethylenetriaminesilver(I) perchlorate, Ag(C4H13N3)(ClO4)
Zhu, HL
Shao, SC
Ma, JL
Qiu, XY
Yang, S
Sun, L
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2003, 218 (04): : 499 - 500
[10] C8H24N4（ClO4）4和C8H24N4（NO3）4·2H2O的合成与性能
刘威
苟晓东
郭晓壮
杨彩
含能材料, 2024, 32 (11) : 1138 - 1144

← 1 2 3 4 5 →