A comparative study on current/capacitance: voltage characteristics of Au/n-Si (MS) structures with and without PVP interlayer

In order to determine the Polyvinylpyrrolidone (PVP) effect on electrical characteristics, Au/n-Si (MS) structures with and without PVP interfacial layer were fabricated. After that their main electrical parameters were extracted from the forward and reverse biases I–V, and C/G–V measurements at room temperature. The experimental characteristics (I–V) show the MPS structure with high rectification ratio (RR = IF/IR at ± 4V), shunt resistance (Rsh) and zero-bias barrier height (ΦB0) and lower leakage current, ideality factor (n), surface states (Nss) compared with the MS structure. RR and the reverse saturation current (Io) for MPS are 55 times higher and 54 times lower than RR and Io for MS, respectively. The voltage dependent n, effective barrier height (Φe) and energy dependent profile of Nss for two types structures are acquired by considering the forward biases I–V data. They were found vary from 1.074 × 1012 eV−1cm−2 (at Ec − 0.821 eV) to 3.55 × 1013 eV−1cm−2 (at Ec − 0.409 eV) for MPS and 3.85 × 1013 eV−1cm−2 (at Ec − 0.724 eV) to 5.67 × 1013 eV−1cm−2 (at Ec-0.405 eV) for MS structure. Rs, n and ΦB0 parameters were also found from the Cheung function as 272.4 Ω, 6.17, and 0.964 eV for MPS and 79.2 Ω, 3.38, and 0.708 eV for MS structure as second way. Some electrical parameters of the structures such as concentration of donor atoms (ND), Fermi energy level (EF) and BH were also found reverse bias C−2–V characteristics for 100 kHz. The use of PVP polymer interlayer considerably improves the efficiency of the MS structure. The way to replace the traditional insulator interlayer concluded as; reducing the Nss alternatively, leakage current and increase of RR, ΦB0, and Rsh, respectively.