To allow for the formation of a high temperature inside the solar cell in order to release gamma rays and split single photons into pair-photons, a very thin layer of complex photopolymer ((chloro-trifluoro-ethylene vinyl ether fluoropolymer binder and dimethacrylic perfluoropolyether oligomer) is layered up on top of the fine silicon printable solar cell. With the PerkinElmer® Lambda 25 UV–Vis Spectrometer, all released conserved quantum numbers (photon to electron and positron, basic kinematics, and energy transfer) are being monitored during this pair-photon production because the conservation of photon momentum is one of the main constraints for this process of breaking down photon particles. Subsequently, the measurement of the required photon frequency (f), and wavelength (λ) to form these pair-photons by the induction of gamma-ray has also been determined to design high-performance solar cells by using MATLAB software. Accordingly, the study revealed that the photopolymer-coated printable solar cell does release the gamma-ray to form pair-photon e+e- in order to release energy with the efficiency of 44.2% that needs to have only the photonic wavelength (λ) of 1.21 × 10−12 m, and frequency (f) of 2.5 × 1020 Hz to release energy 1,024,000 eV, which is equivalent to energy 7.253 kWh/m2. The results suggested that solar cells profoundly release the gamma-ray due to the presence of a photopolymer which initiates high temperature inside the solar cell and paves the photon-photon collision to produce pair-photons from a single one. Subsequently, photon to electron and positron, its basic kinematics have also been monitored during this photon-photon interaction to determine the energy transfer to design high-performance solar cells.