Ionic conductivity of mixed phosphates of the composition Li3 − 2xNbxIn2 − x(PO4)3

被引：0
|
作者：
A. R. Shaikhlislamova
A. B. Yaroslavtsev
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Inorganic Materials | 2008年 / 44卷
关键词：
Zirconium Phosphate; Lithium Content; Heterovalent Substitution; Lithium Zirconium; High Lithium Content;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The properties of Li3 − 2xNbxIn2 − x(PO4)3 phosphates have been studied by impedance spectroscopy, x-ray diffraction, and electron microscopy. The effect of heterovalent substitution on the thermal expansion and lattice parameters of the phosphates has been examined. Their electrical conductivity is shown to rise in going from Li0.6Nb1.2In0.8(PO4)3 to LiNbIn (PO4)3 and from Li1.2Nb0.9In1.1(PO4)3 to Li3In2(PO4)3, which can be accounted for by consecutive filling of the M(1) and M(2) sites in the structure of the phosphates.
引用
收藏
相关论文
共 50 条
  • [21] Ionic motion in Li3In2(PO4)3
    Pronin, I.S., 1600, (38): : 1 - 2
  • [22] IONIC MOTION IN LI3IN2(PO4)3
    PRONIN, IS
    SIGARYOV, SE
    VASHMAN, AA
    SOLID STATE IONICS, 1990, 38 (1-2) : 9 - 24
  • [23] Anisotropy of ionic conductivity in Li3Fe2(PO4)(3) single crystals
    IvanovSchitz, AK
    Timofeeva, VA
    CRYSTALLOGRAPHY REPORTS, 1997, 42 (03) : 435 - 437
  • [24] Synthesis and lithium ionic conductivity of Li3-2x(In1-xZrx)2(PO4)3 (0≤x≤0.20)
    Yoshikawa, K
    Hayakawa, N
    Suzuki, T
    Uematsu, K
    Toda, K
    Sato, M
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (6-7) : 879 - 882
  • [25] PHASE-TRANSITIONS AND IONIC-CONDUCTION IN 3D SKELETON PHOSPHATES LI3CR2(PO4)3, LI3FE2(PO4)3, NA3CR2(PO4)3, NA3FE2(PO4)3, AG3CR2(PO4)3, AG3FE2(PO4)3, K3CR2(PO4)3, K3FE2(PO4)3
    DYVOIRE, F
    PINTARDSCREPEL, M
    BRETEY, E
    DELAROCHERE, M
    SOLID STATE IONICS, 1983, 9-10 (DEC) : 851 - 857
  • [26] Ionic conductivity and crystal structure for the Li3-2xCr2-xTax(PO4)3 system
    Aono, H
    bin Idris, MA
    Sadaoka, Y
    SOLID STATE IONICS, 2004, 166 (1-2) : 53 - 59
  • [27] A mixed α/β superstructure in NASICON ionic conductors:: Neutron diffraction study of Li2FeTi(PO4)3 and Li2FeZr(PO4)3
    Catti, M
    JOURNAL OF SOLID STATE CHEMISTRY, 2001, 156 (02) : 305 - 312
  • [28] DISORDER OF PO4 TETRAHEDRA AND IONIC-CONDUCTIVITY OF NA3IN2(PO4)3
    SIGARYOV, SE
    VASILIEV, AB
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1991, 52 (03) : 467 - 470
  • [29] Evolution of microstructure and its relation to ionic conductivity in Li1+xAlxTi2-x(PO4)3
    Hupfer, Thomas
    Bucharsky, Ethel C.
    Schell, Karl G.
    Senyshyn, Anatoliy
    Monchak, Mykhailo
    Hoffmann, Michael J.
    Ehrenberg, Helmut
    SOLID STATE IONICS, 2016, 288 : 235 - 239
  • [30] IONIC-CONDUCTIVITY IN THE SYSTEM NAZR2(PO4)3-NA3Y2(PO4)3
    NAGAI, M
    FUJITSU, S
    KANAZAWA, T
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1980, 63 (7-8) : 476 - 477
12345