Spectroscopic and quantum chemical investigation of the 4Bi2O3 · B2O3 glass structure

被引：0
|
作者：
S. Rada
E. Culea
V. Rus
机构：
[1] Technical University of Cluj-Napoca,Department of Physics
来源：
Journal of Materials Science | 2008年 / 43卷
关键词：
Fermi Level; B2O3; Bi2O3; Glass Network; Boroxol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The structural properties of the 4Bi2O3 · B2O3 glass were investigated by FT-IR spectroscopy and quantum chemical calculations. The main results reveal that the coordination polyhedrons of the bismuth ion from the [BiO6] structural units and of the boron ion from the [BO4] groups are irregular. Accordingly, the [BiO6] and [BO4] structural units in the studied glass matrix have a complex structural role that makes possible the formation of the vitreous system.
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页码：6094 / 6098
页数：4
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