Liquid–liquid extraction of neodymium (III) and europium (III) using synergic mixture of furosemide and tribenzylamine in benzyl alcohol

被引:0
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作者
YA Abbasi
S. Shahida
A. Ali
MH Khan
MI Khan
机构
[1] The University of Azad Jammu and Kashmir,Department of Chemistry
[2] Government Degree College Bagh,Department of Chemistry
[3] The University of Poonch Rawalakot,Chemistry Division
[4] Women University of Azad Jammu and Kashmir Bagh,Department of Chemistry
[5] Pakistan Institute of Nuclear Science and Technology,undefined
[6] The Islamia University of Bahawalpur,undefined
关键词
Liquid-liquid extraction; Nd(III); Eu(III); Furosemide; Tribenzylamine; Benzyl alcohol;
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摘要
The extraction behavior of Nd(III) and Eu(III) with 0.05 mol dm−3 furosemide in benzyl alcohol as single acidic extractant and then with equimolar (0.05 mol dm−3) synergic mixture of furosemide as acidic extractant and tribenzylamine as neutral donor in benzyl alcohol has been studied from aqueous solutions of pH 1 to 6. The effect of various parameters and of various cations and anions on the extraction of these metal ions was investigated. The composition of the extracted adducts was determined by slope analysis method that came out to be [(M(FS)2)+ (CH3COO)−] and [M(FS)3·3TBA] where M = Nd(III) and Eu(III).
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页码:273 / 282
页数:9
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