Statistical thermodynamics of model polar fluids

被引：0
|
作者：
G. B. Litinskii
机构：
[1] Kharkov National Technical University (KhPI),Military Department
来源：
High Temperature | 2010年 / 48卷
关键词：
Internal Energy; Near Neighbor; Neighbor Interaction; Infinite Chain; Spherical Approximation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The high-temperature behavior of model fluids of dipolar (DHS) and quadrupole (QHS) hard spheres is considered using the model of hindered rotation of molecules. It is demonstrated that, at some (critical) temperature, a percolation transition associated with disintegration of infinite chain is possible in DHS fluid. As to QHS fluid, the spatial gel-like structure is retained at all temperatures; it is only the “functionality” of particles that varies.
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页码：29 / 34
页数：5
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