Low-Temperature Template Synthesis of [4,6,6-Trimethyl-2,6-dithioxo-3,7-diazanon-4-enebis(imidothioato)]copper(II) in Gelatin-Immobilized Cu2[Fe(CN)6] Matrix Materials

被引：0

作者：

O. V. Mikhailov

机构：

[1] Kazan State Technological University,

[2] Kazan,undefined

来源：

Russian Journal of General Chemistry | 2001年 / 71卷

关键词：

Copper; Aqueous Solution; Acetone; Matrix Material; Hexacyanoferrate;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Complexation in gelatin-immobilized copper(II) hexacyanoferrate(II) matrices on contact withalkaline (pH 10) aqueous solutions containing dithiooxamide, acetone was studied. Under these conditions'template synthesis occurs to give the chelate CuL [L is 4,6,6-trimethyl-2,6-dithioxo-3,7-diazanon-4-enebis-(imidothioato) ligand], with dithiooxamide and acetone acting as ligand synthons. The reaction pattern was suggested. Attempted reaction of dithiooxamide and acetone in solution in the absence of Cu(II) does not yield this ligand.

引用

页码：1676 / 1681

页数：5

共 28 条

[1] Low-temperature template synthesis of [4,6,6-trimethyl-2,6-dithioxo-3,7-diazanon-4-enebis(imidothioato)]copper(II) in gelatin-immobilized CU2[Fe(CN)6] matrix materials
Mikhailov, OV
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (11) : 1676 - 1681
[2] Mild template synthesis of a copper(II)-containing macrocyclic compound with 4,4,6-trimethyl-2,3,7,8-tetraazanonen-6-dithiohydrazide-1,9 in a gelatin-immobilized matrix
Oleg V. Mikhailov
Marina A. Kazymova
Tatyana A. Shumilova
Svetlana S. Solovieva
Transition Metal Chemistry, 2003, 28 : 665 - 667
[3] Ni(II)- and Cu(II)-containing heterocyclic compounds with 4,4′,6-trimethyl-2,8-dithio-3,7-diazanonen-6-dithioamide-1,9 obtained in gelatin-immobilized matrices in the template synthesis process
Mikhailov, OV
Kazymova, MA
Shumilova, TA
Vafina, LR
HETEROCYCLIC COMMUNICATIONS, 2000, 6 (04) : 357 - 362
[4] Mild template synthesis of a copper(II)-containing macrocyclic compound with 4,4,6-trimethyl-2,3,7,8-tetraazanonen-6-dithiohydrazide-1,9 in a gelatin-immobilized matrix
Mikhailov, OV
Kazymova, MA
Shumilova, TA
Solovieva, SS
TRANSITION METAL CHEMISTRY, 2003, 28 (06) : 665 - 667
[5] Complexing of Cu(II) with N,N′-diphenylthiooxamide and N,N′-diphenyldithiooxamide in a gelatin-immobilized Cu2[Fe(CN)6] matrix
Mikhailov, OV
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2003, 73 (07) : 1010 - 1015
[6] Complexing of Cu(II) with N,N'-Diphenylthiooxamide and N,N'-Diphenyldithiooxamide in a Gelatin-Immobilized Cu2[Fe(CN)6] Matrix
O. V. Mikhailov
Russian Journal of General Chemistry, 2003, 73 : 1010 - 1015
[7] Soft template synthesis of macrocyclic copper(II) chelates with 3,9-dithio-4,8-diaza-6-oxaundekandithioamide-1,11 in a Cu2[Fe(CN)6]-gelatin-immobilized matrix
Mikhailov, OV
Kazymova, MA
Shumilova, TA
Solovieva, SS
Mannafov, TG
TRANSITION METAL CHEMISTRY, 2003, 28 (05) : 592 - 594
[8] Soft template synthesis of macrocyclic copper(II) chelates with 3,9-dithio-4,8-diaza-6-oxaundekandithioamide-1,11 in a Cu2[Fe(CN)6]-gelatin-immobilized matrix
Oleg V. Mikhailov
Marina A. Kazymova
Tatyana A. Shumilova
Svetlana S. Solovieva
Tafkil G. Mannafov
Transition Metal Chemistry, 2003, 28 : 592 - 594
[9] Mild Template Synthesis of (2,8-Dithio-3,7-diaza-4,6-dimethyl-5-oxanonanedithioamido-1,9)copper(II) in Cu2[Fe(CN)6] Gelatin-Immobilized Matrices
O. V. Mikhailov
Russian Journal of Coordination Chemistry, 2002, 28 : 363 - 368
[10] Mild Template Synthesis of (2,7-Dithio-3,6-Diazaoctadiene-3,5-Dithioamido-1,8) copper(II) at Cu2[Fe(CN)6] Gelatin-immobilized Matrices
Mikhailov, O. V.
Khamitova, A. I.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1998, 24 (09) : 629 - 633

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