Nanoporous Crystalline Material CsLiB6O10

被引:0
|
作者
N. G. Kononova
A. E. Kokh
P. P. Fedorov
M. S. Ferapontova
R. M. Zakalyukin
E. A. Tkachenko
机构
[1] Institute of Mineralogy and Petrography,
[2] Siberian Division,undefined
[3] Russian Academy of Sciences,undefined
[4] Shubnikov Institute of Crystallography,undefined
[5] Russian Academy of Sciences,undefined
来源
Inorganic Materials | 2002年 / 38卷
关键词
Hydrolysis; Hydration; Acetone; Inorganic Chemistry; Crystalline Material;
D O I
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中图分类号
学科分类号
摘要
CsLiB6O10 crystals up to 60 × 40 × 20 mm in dimensions were prepared by top-seeded solution growth, and their interaction with water was studied. The crystals were found to be subject to hydration followed by hydrolysis, during which water leaches Cs from the structural channels to yield Cs2B10O16 · 8H2O as the final product. The channel dimensions are not large enough to incorporate ethanol or acetone molecules.
引用
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页码:1264 / 1269
页数:5
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