Formation of “three-bridge” cobalt-copper commo-cluster with the (B-H)3...Cu bond in the reaction of [Cs][commo-3,3′-Co(1,2-C2B9H11)2] with copper(i) and copper(ii) compounds

被引：0
|
作者：
E. V. Balagurova
I. V. Pisareva
I. A. Godovikov
A. F. Smol’yakov
F. M. Dolgushin
I. T. Chizhevsky
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2013年 / 62卷
关键词：
binuclear cobalt-copper carborane clusters; synthesis; dynamic behavior in solution; crystal structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Zwitterionic 4,8,8′-exo-{Ph3PCu}-4,8,8′-(μ-H)3-commo-3,3′-Co(1,2-C2B9H9)-(1′,2′-C2B9H10) and ionic [(PPh3)3Cu][commo-3,3′-Co(1,2-C2B9H11)2 complexes were synthesized in moderate yields by the reaction of anionic commo-complex [Cs][commo-3,3′-Co-(1,2-C2B9H11)2]) in a CH2Cl2 solution with anhydrous CuCl2 or CuCl in the presence of PPh3. The complexes were also synthesized by alternative methods and characterized by NMR and X-ray diffraction methods.
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页码：548 / 553
页数：5
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