Reactions of Bi-, Tri-, and tetracyclic amines with succinic anhydride

被引：0
|
作者：
L. I. Kas’yan
A. V. Serbin
A. O. Kas’yan
D. V. Karpenko
E. A. Golodaeva
机构：
[1] Dnepropetrovsk National University,Scientific and Innovation Health Foundation
[2] Biomodulator and Drug Research Center,undefined
[3] ProBioGen AG,undefined
[4] Kirovograd State Pedagogical University,undefined
来源：
Russian Journal of Organic Chemistry | 2008年 / 44卷
关键词：
Norbornene; Succinimide; Succinic Anhydride; Oily Substance; Phthalic Anhydride;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Succinic anhydride reacted with cage-like amines {bicyclo[2.2.1]hept-5-en-exo-and-endo-2-yl-methanamines, 2-(bicyclo[2.2.1]hept-5-en-endo-2-yl)ethanamine, exo-5,6-epoxybicyclo[2.2.1]heptan-exo-2-yl-methanamine, tetracyclo[6.2.1.13,6.02,7]dodec-9-en-endo-4-ylmethanamine, 1-(bicyclo[2.2.1]heptan-2-yl)ethanamine, and 4-azatricyclo[5.2.1.02,6]dec-8-ene} to give the corresponding amido acids having a cage-like fragment. The latter were converted into carboximides by the action of hexamethyldisilazane in boiling benzene in the presence of zinc(II) chloride and then into epoxy derivatives. The structure of the newly synthesized compounds was confirmed by IR and NMR spectroscopy.
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页码：340 / 347
页数：7
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