Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(η2–C60)(CO)2(dpphen)(dbf)·0.63CS2] (dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate)

被引：0
|
作者：
Xiangjin Xie
Xianglin Jin
Kaluo Tang
机构：
[1] Peking University,Institute of Physical Chemistry, College of Chemistry and Molecular Engineering
来源：
Transition Metal Chemistry | 2003年 / 28卷
关键词：
Physical Chemistry; Crystal Structure; Inorganic Chemistry; Molybdenum; Fullerene;
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摘要：
The molybdenum complex [Mo(η2-C60)(CO)2(dpphen)(dbf)] (1) [dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate] has been prepared and structurally characterized by X-ray diffraction analysis. In the molecule of (1), the coordination geometry of the Mo atom is distorted octahedral with the phen (1,10-phenanthroline) group of dpphen and two CO groups in the equatorial plane. The Mo atom binds in an η2-fashion to the C—C bonds of C60and dbf. The two C—C bonds are almost mutually orthogonal.
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页码：741 / 744
页数：3
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