Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(η2–C60)(CO)2(dpphen)(dbf)·0.63CS2] (dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate)

被引：0

作者：

Xiangjin Xie

Xianglin Jin

Kaluo Tang

机构：

[1] Peking University,Institute of Physical Chemistry, College of Chemistry and Molecular Engineering

来源：

Transition Metal Chemistry | 2003年 / 28卷

关键词：

Physical Chemistry; Crystal Structure; Inorganic Chemistry; Molybdenum; Fullerene;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The molybdenum complex [Mo(η2-C60)(CO)2(dpphen)(dbf)] (1) [dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate] has been prepared and structurally characterized by X-ray diffraction analysis. In the molecule of (1), the coordination geometry of the Mo atom is distorted octahedral with the phen (1,10-phenanthroline) group of dpphen and two CO groups in the equatorial plane. The Mo atom binds in an η2-fashion to the C—C bonds of C60and dbf. The two C—C bonds are almost mutually orthogonal.

引用

页码：741 / 744

页数：3

共 24 条

[1] Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(η2-C60)(CO)2(dpphen)(dbf) • 0.63CS2](dpphen=4,7-diphenyl-1,10-phenanthroline; dbf= dibutyl fumarate)
Xie, XJ
Jin, XL
Tang, KL
TRANSITION METAL CHEMISTRY, 2003, 28 (07) : 741 - 744
[2] Synthesis and structures of bis(alkene) complexes of tungsten and molybdenum, [M(CO)2(dpphen)(dbf)2] (M = W or Mo; dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutylfumarate)
Xie, XJ
Jin, XL
Tang, KU
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (11): : 2481 - 2485
[3] Mixed-ligand complexes with 2,6-pyridinedicarboxylato(2-) and 4,7-diphenyl-1,10-phenanthroline ligands, [MII(pdc)(DPphen)(H2O)].H2O (M = Co or Cu).: Synthesis, crystal structures and properties
Brandi-Blanco, MP
Choquesillo-Lazarte, D
González-Pérez, JM
Castiñeiras, A
Niclós-Gutiérrez, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (11): : 2081 - 2085
[4] CRYSTAL AND MOLECULAR-STRUCTURE OF [CU(2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE)2]BF4.CH3OH
KLEMENS, FK
FANWICK, PE
BIBLER, JK
MCMILLIN, DR
INORGANIC CHEMISTRY, 1989, 28 (15) : 3076 - 3079
[5] The crystal structure of molybdenum complex of [60] fullerene Mo(η2-C60) (CO)2 (phen) (dbm)
Cui, P.
Jin, X.
Xie, X.
Tang, K.
Beijing Daxue Xuebao Ziran Kexue Ban/Acta Scientiarum uaturalium Universitatis Pekinensis, 2001, 37 (06): : 875 - 879
[6] The crystal structure of the molybdenum complex of [70]fullerene Mo(η2-C70)(CO)2(phen)(dbm)•2C3H8O•2.5H2O (phen = 1,10-phenanthroline, dbm = dibutyl maleate)
Cui, P
Li, L
Tang, KL
Jin, XL
JOURNAL OF CHEMICAL RESEARCH-S, 2001, (06): : 240 - 242
[7] Synthesis, characterization, and crystal structure determination of two mercury(II) dimer complexes with 4,7-diphenyl-1,10-phenanthroline, 5,5'-dimethyl-2,2'-bipyridine and bromide
Alizadeh, Robabeh
Amani, Vahid
Farshady, Ali Akbar
Khavasi, Hamid Reza
JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (12) : 2122 - 2131
[8] Affinity of a new copper(II) complex to DNA/BSA and antioxidant/radical scavenging activities: crystal structure of [Cu(4,7-diphenyl-1,10-phenanthroline)(leucine)(NO3)(H2O)]
Inci, Duygu
Aydin, Rahmiye
Zorlu, Yunus
JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (18) : 2677 - 2696
[9] The redox behaviour of the family (C60)[Mo(CO)2(phen)(dbm)]n (n=1-3) -: A comparison with the analog (η2-C70)[Mo(Co)2(phen)(dbm)] (phen=1,10-phenanthroline; dbm = dibutyl maleate)
Zanello, P
Laschi, F
Cinquantini, A
Fontani, M
Tang, K
Jin, XL
Li, L
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (06) : 1345 - 1350
[10] CRYSTAL STRUCTURE OF SOME DICARBONYL ALLYL DERIVATIVES OF SUBSTITUTED CARBONYLS OF MOLYBDENUM .2. CRYSTAL STRUCTURE OF (ISOTHIOCYANATO)DICARBONYL-1,10-PHENANTHROLINE(2-METHYLALLYL)MOLYBDENUM NCS(CO)2-(C12H8N2)(C4H7)MO
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FENN, RH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 25 (01) : 173 - &

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