3D Supramolecular structure of the coordination polymer [Ag(2-MePyz)ReO4]

被引：0
|
作者：
Yu. V. Kokunov
Yu. E. Gorbunova
V. V. Kovalev
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Coordination Chemistry | 2012年 / 38卷
关键词：
Coordination Polymer; Perrhenate; Silver Complex; Supramolecular Framework; Linear Coordination;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The complex [Ag(2-MePyz)ReO4] (I) is synthesized, and its structure is determined. The crystals are monoclinic, space group P 21/c, a = 7.234(1), b = 15.451(1), c = 8.036(3) Å, β = 92.56(1)°, V = 897.3(2) Å3, ρcalcd = 3.347 g/cm3, Z = 4. Structure I consists of cationic polymer chains [Ag(2-MePyz)]∞+. Anions ReO4− are weakly bound to Ag+ (Ag...Oaverage 2.693 Å) and join the latter into a supramolecular framework. The Ag+ ion has a linear coordination (NAgN 177.9(2)°, distances Ag-N 2.223(5) and 2.242(5) Å).
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页码：245 / 248
页数：3
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