Crystal structure of K4MnMo4O15 — A parent compound of a new isostructural series of complex oxides K4M2+Mo4O15 (M2+ = Mn, Mg, Co, Cd)

被引：0
|
作者：
S. F. Solodovnikov
E. S. Zolotova
Z. A. Solodovnikova
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Branch
来源：
Journal of Structural Chemistry | 1997年 / 38卷
关键词：
CaMoO4; Potassium Atom; Equivalent Isotropic Thermal Parameter; Glaserite; Isostructural Series;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The structure of K4MnMo4O15 was solved from single-crystal X-ray diffraction data (a = 10372, c = 8.160 Å, Z = 2, space group P-3, 2152 reflections, R = 0.039). The structure is of new, glaserite-like, type. A characteristic and original feature of the structure is a Mn(II)O6 octahedron with six MoO4 tetrahedra attached to it by their vertices; the octahedron is linked with a MoO6 octahedron by a common face. The MoO4 tetrahedra bridge the octahedral dimers with each other, forming lacy layers with potassium atoms lying between the layers. K4M2+Mo4O15 (M2+= Mg, Co, Cd) phases, which have similar structures, have been synthesized and characterized.
引用
收藏
页码：83 / 88
页数：5
相关论文
共 50 条
  • [21] Crystal structure of M4[(UO2)2C2O4(SO4)2(NCS)2] (M = K+, Rh+) and K4[(UO2)2C2O4(SeO4)2(NCS)2]
    Medrish, I. V.
    Peresypkina, E. V.
    Virovets, A. V.
    Serezhkina, L. B.
    CRYSTALLOGRAPHY REPORTS, 2008, 53 (03) : 462 - 465
  • [22] The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)
    Weil, Matthias
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : I75 - U85
  • [23] Continuous recovery of uranium oxides by electrolysis of M2MoO4-M2Mo2O7-UO2MoO4 melts (M = Li, Na, K, Cs)
    V. K. Afonichkin
    L. G. Khrustova
    V. E. Komarov
    Russian Journal of Applied Chemistry, 2013, 86 : 133 - 140
  • [24] Continuous recovery of uranium oxides by electrolysis of M2MoO4-M2Mo2O7-UO2MoO4 melts (M = Li, Na, K, Cs)
    Afonichkin, V. K.
    Khrustova, L. G.
    Komarov, V. E.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2013, 86 (02) : 133 - 140
  • [25] Crystal structure and vibrational spectra of M[VO2(SeO 4)(H2O)2]·H2O (M = K, Rb, NH4)
    Tyutyunnik A.P.
    Zubkov V.G.
    Krasil'Nikov V.N.
    Berger I.F.
    Perelyaeva L.A.
    Baklanova I.V.
    Skripkin M.Yu.
    Svensson G.
    Journal of Structural Chemistry, 2011, 52 (2) : 350 - 357
  • [26] Hydrogen-bonding interactions in the series of complexes [M(C4O4)(OH2)2(dmf)2] and [M(C4O4)(OH2)4] (M = Mn, Co, Ni, Cu, Zn)
    Alleyne, BD
    Hall, LA
    Hosein, HA
    Jaggernauth, H
    White, AJP
    Williams, DJ
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (22): : 3845 - 3850
  • [27] CRYSTAL-STRUCTURE OF HO2MO4O15 HOLMIUM TETRAMOLYBDATE
    EFREMOV, VA
    DAVYDOVA, NN
    GOKHMAN, LZ
    EVDOKIMOV, AA
    TRUNOV, VK
    ZHURNAL NEORGANICHESKOI KHIMII, 1988, 33 (12): : 3005 - 3010
  • [28] PREPARATION, STRUCTURE AND BEHAVIOR OF PEROXOMOLYBDATE [K4MO4O12(O2)2] AND PEROXOTUNGSTATE [K4W4O12(O2)2.4H2O]
    JIANG, AR
    JIANG, T
    PANG, Z
    ACTA CHIMICA SINICA, 1989, 47 (08) : 800 - 803
  • [29] Structural features in Tutton's salts K2[M2+(H2O)6](SO4)2, with M2+ = Mg, Fe, Co, Ni, Cu, and Zn
    Bosi, Ferdinando
    Belardi, Girolamo
    Ballirano, Paolo
    AMERICAN MINERALOGIST, 2009, 94 (01) : 74 - 82
  • [30] Synthesis of Double Uranyl Phthalates of the M4[(UO2)4(μ3-O)2(C6H4C2O4)4] ⋅ nH2O Type with M = NH4, K, and Cs. Crystal Structure of K4[(UO2)4O2(C6H4C2O4)4] ⋅ 3H2O
    I. A. Charushnikova
    N. N. Krot
    I. N. Polyakova
    V. I. Makarenkov
    Radiochemistry, 2005, 47 (3) : 241 - 246
12345