Thermal behaviour of cardanol-based benzoxazinesMonomers and polymers

被引:0
|
作者
Bimlesh Lochab
Indra K. Varma
Jayashree Bijwe
机构
[1] IIT,Industrial Tribology Machine Dynamics and Maintenance Engineering Centre (ITMMEC)
[2] Delhi,Centre for Polymer Science and Engineering (CPSE)
[3] IIT,undefined
[4] Delhi,undefined
关键词
Benzoxazine; Cardanol; Brookfield viscosity; Renewable; Curing; Thermal stability;
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中图分类号
学科分类号
摘要
A novel benzoxazine monomer (Bz-C) based on agrochemical renewable resource—cardanol (by-product of cashew nut tree, Anacardium occidentale) was synthesized. Bz-C, a liquid monomer, was used as reactive diluent for the solventless synthesis of bisphenol-A benzoxazine monomer (Bz-A). Benzoxazine monomer based on cardanol and bisphenol-A in 3:1, 1:1 and 1:3 blend ratio were prepared by this method. The resins had Brookfield viscosity at 316 K in the range of 145–81,533 mPa s. The resins were characterized by 1H-NMR, FTIR and elemental analysis. Curing characteristics were studied by DSC analysis. Thermal stability of cured resins was found to improve with increase in Bz-C content in the blends.
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页码:769 / 774
页数:5
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