Methyl (3R,5R)-3,5-dihydroxydecanoate in the asymmetric synthesis of Idea Leuconoe pheromone and formal syntheses of (+)-(3R,5R)-3-hydroxydecano-5-lactone, verbalactone, and Tolypothrix pentaether

被引：0
|
作者：
I. V. Mineeva
机构：
[1] Belarusian State University,
来源：
Russian Journal of Organic Chemistry | 2013年 / 49卷
关键词：
TsOH; Mevinolin; Anhydrous Diethyl Ether; Anhydrous Methylene Chloride; Formal Synthesis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A simple and efficient asymmetric synthesis of (5S,7R)-7-hydroxydodecano-5-lactone, a component of the giant danaine butterfly Idea leuconoe pheromone, and formal syntheses of (+)-(3R,5R)-3-hydroxydecano-5-lactone, verbalactone, and Tolypothrix pentaether have been accomplished starting from methyl (3R,5R)-3,5-dihydroxydecanoate. The latter is obtained from methyl 3-[(tributylstannyl)methyl]but-3-enoate using Keck allylation in the key step of the construction of its carbon skeleton.
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页码：838 / 842
页数：4
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