Effect of H/D isotope substitution on polarizability of methanol molecules

被引：0
|
作者：
E. V. Ivanov
V. K. Abrosimov
机构：
[1] Russian Academy of Sciences,Institute of Chemistry of Solutions
来源：
Russian Chemical Bulletin | 2005年 / 54卷
关键词：
methanol; polarizability of molecules; H/D isotope effects;
D O I：
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摘要：
The electron polarizabilities (α0·1024/cm3 molec.−1) were estimated from the data on refractive indices and molar volumes of H/D isotopomers of methanol at 25 °C using the Lorentz-Lorentz formula: 3.265 (CH3OH), 3.260 (CH3OD), 3.235 (CD3OH), and 3.231 (CD3OD). A relationship between the isotope effects for α0 and volume (packing) changes in the structure of liquid methanol induced by deuterosubstitution in the methanol molecule was proposed.
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页码：1987 / 1988
页数：1
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