Synthesis and Characterization of 1,8-bis(ferrocenylmethyl)-5,5,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, a Macrocyclic Ligand and its Complexes

被引：0
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作者：
Wen Ma
Yu-Peng Tian
Sheng-Yi Zhang
Jie-Ying Wu
Hoong-Kun Fun
Suchada Chantrapromma
机构：
[1] Anhui University,Department of Chemistry
[2] Universiti Sains Malaysia,X
来源：
Transition Metal Chemistry | 2006年 / 31卷
关键词：
Hydrogen; Mass Spectrum; Catalysis; Absorption Spectrum; Hydrogen Atom;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new diferrocenyl-substituted macrocyclic ligand (H2L) and its complexes ML(M = CuII, NiII, ZnII, CdII) were prepared and characterized by IR, elemental analysis, absorption spectra and FAB mass spectra. The ferrocenyl-substituted macrocyclic ligand was characterized by single crystal X-ray diffraction analysis. The superconjugative effect of the cyclopentadienyl (CP) rings increase the activity of the hydrogen atoms in the tetra-azacyclotetradecane macrocyclic ligand. The imine nitrogen atoms lose two protons and coordinate to the metal. The electrochemical properties of these compounds are discussed.
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页码：97 / 102
页数：5
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