NOx-Catalyzed Gas-Phase Activation of Methane: A Reaction Study

被引：0
|
作者：
Zhen Yan
Chao-Xian Xiao
Yuan Kou
机构：
[1] Peking University,College of Chemistry and Molecular Engineering
来源：
Catalysis Letters | 2003年 / 85卷
关键词：
gas-phase oxidation; methane activation; NO; syngas; ethylene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The catalytic effect of NOx on methane oxidation in the absence of any solid catalyst has been investigated. The experimental results show that NOx has very good catalytic activity in the partial oxidation of methane. The predominant products for reactions in a CH4-O2-NOx co-feed mode are CO, CO2, H2O and H2, CH3OH, HCHO, and C2H4. Aromatics are also observed.
引用
收藏
页码：129 / 133
页数：4
相关论文
共 50 条
  • [41] Gas-Phase Selective Oxidation of Methane into Methane Oxygenates
    Xu, Zhen Chao
    Park, Eun Duck
    CATALYSTS, 2022, 12 (03)
  • [42] METHANE GAS-PHASE DYNAMICS IN MARINE SEDIMENTS: A MODEL STUDY
    Mogollon, Jose M.
    L'Heureux, Ivan
    Dale, Andrew W.
    Regnier, Pierre
    AMERICAN JOURNAL OF SCIENCE, 2009, 309 (03) : 189 - 220
  • [43] NOx-catalyzed ozone destruction and NOx activation at midlatitudes to high latitudes as the main cause of the spring to fall ozone decline in the Northern Hemisphere
    Brühl, C
    Crutzen, PJ
    JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2000, 105 (D10) : 12163 - 12168
  • [44] A computational study on the intriguing mechanisms of the gas-phase thermal activation of methane by bare [Ni(H)(OH)]+
    Lakuntza, O.
    Matxain, J. M.
    Ruiperez, F.
    Besora, M.
    Maseras, F.
    Ugalde, J. M.
    Schlangen, M.
    Schwarz, H.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (26) : 9306 - 9310
  • [45] GAS-PHASE PYROLYSES OF ALKYL AZIDES - GAS-PHASE REACTION .68. EXPERIMENTAL-EVIDENCE FOR CHEMICAL ACTIVATION
    BOCK, H
    DAMMEL, R
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (16) : 5261 - 5269
  • [46] C-2+ HYDROCARBONS IN THE HOMOGENEOUS GAS-PHASE REACTION OF METHANE AND OXYGEN
    ZANTHOFF, H
    BAERNS, M
    CHEMIE INGENIEUR TECHNIK, 1989, 61 (08) : 625 - 627
  • [47] PRODUCTS OF THE OH RADICAL-INITIATED GAS-PHASE REACTION OF FLUORENE IN THE PRESENCE OF NOX
    HELMIG, D
    AREY, J
    ATKINSON, R
    HARGER, WP
    MCELROY, PA
    ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1992, 26 (09): : 1735 - 1745
  • [48] STUDIES OF GAS-PHASE AND LI/TIO2 CATALYZED OXIDATIVE COUPLING OF METHANE
    LANE, GS
    WOLF, EE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 196 : 33 - FUEL
  • [49] CATALYTIC GAS-PHASE REACTION
    YONEDA, Y
    KOGYO KAGAKU ZASSHI, 1961, 64 (10): : 1702 - &
  • [50] Theoretical study on the reaction of magnesium with water in the gas-phase
    Yang, Weijuan
    Han, Zhijiang
    Zhou, Junhu
    Liu, Jianzhong
    Cen, Kefa
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (17) : 10608 - 10613
12345