Functional Acetal Methacrylates: III. Electrophilic Addition of Diols to 2-(Vinyloxy)ethyl Methacrylate

被引：0
|
作者：
O. V. Vysotskaya
L. A. Oparina
L. N. Parshina
N. K. Gusarova
B. A. Trofimov
机构：
[1] Russian Academy of Sciences,Faworsky Irkutsk Institute of Chemistry, Siberian Division
来源：
Russian Journal of Organic Chemistry | 2002年 / 38卷
关键词：
Glycerol; Propane; Glycol; Methacrylate; Diol;
D O I：
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中图分类号：
学科分类号：
摘要：
Reactions of 2-(vinyloxy)ethyl methacrylate with diols [ethylene glycol, diethylene glycol, triethylene glycol, oligoethylene glycol-400, Z-2-butene-1,4-diol, 2-butyne-1,4-diol, 1,1,3,3-tetramethyl-1,3-bis(3-hydroxypropyl)disiloxane, 2,2-bis(4-hydroxyphenyl)propane] and polyols (glycerol, pentaerythritol) under electrophilic conditions (1 wt% of CF3COOH, 20-60°C, 1-3 h) result in quantitative formation of functional acetal methacrylates.
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页码：1082 / 1087
页数：5
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