Functional Acetal Methacrylates: III. Electrophilic Addition of Diols to 2-(Vinyloxy)ethyl Methacrylate

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作者
O. V. Vysotskaya
L. A. Oparina
L. N. Parshina
N. K. Gusarova
B. A. Trofimov
机构
[1] Russian Academy of Sciences,Faworsky Irkutsk Institute of Chemistry, Siberian Division
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关键词
Glycerol; Propane; Glycol; Methacrylate; Diol;
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摘要
Reactions of 2-(vinyloxy)ethyl methacrylate with diols [ethylene glycol, diethylene glycol, triethylene glycol, oligoethylene glycol-400, Z-2-butene-1,4-diol, 2-butyne-1,4-diol, 1,1,3,3-tetramethyl-1,3-bis(3-hydroxypropyl)disiloxane, 2,2-bis(4-hydroxyphenyl)propane] and polyols (glycerol, pentaerythritol) under electrophilic conditions (1 wt% of CF3COOH, 20-60°C, 1-3 h) result in quantitative formation of functional acetal methacrylates.
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页码:1082 / 1087
页数:5
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