Controlled-Potential Coulometric Determination of Ruthenium in Ru(OH)Cl3 with Microwave Sample Preparation

被引：0
|
作者：
N. A. Ezerskaya
E. S. Toropchenova
D. B. Pachgin
I. N. Kiseleva
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Journal of Analytical Chemistry | 2004年 / 59卷
关键词：
Analytical Chemistry; Microwave; Sample Preparation; Ruthenium; Microwave Irradiation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A procedure for the controlled-potential coulometric (CPC) determination of ruthenium is proposed. The procedure is based on the redox reaction [Ru(CO)Cl5]2–/[Ru(CO)Cl4(H2O)]2– followed by the synthesis of the [Ru(CO)Cl5]2– depolarizing complex under microwave irradiation. The procedure was used in the analysis of a domestic commercial Ru(OH)Cl3 preparation.
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页码：296 / 299
页数：3
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