Monolayers of Supramolecular Cryptate Complexes at the Electrode/Solution Interface

被引:0
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作者
E. V. Stenina
L. N. Sviridova
V. F. Stenin
机构
[1] Lomonosov Moscow State University,Interdepartmental Center for Analytical Research in Physics
[2] Chemistry,undefined
[3] and Biology at Presidium of the Russian Academy of Sciences,undefined
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关键词
electrode; adsorption; adsorption parameters; macropolycyclic ligands; cryptand; electrochemical reaction; differential capacity; potential; electrical double layer;
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摘要
The results of investigation of the electrochemical properties of cryptand 222 from the macropolycyclic ligands group and its complexes with cations were summarized. Emphasis was placed on the properties of the adsorbed layers of these substances at the electrode/solution interface. Adsorption parameters of the compounds studied were calculated in the framework of the Frumkin–Damaskin theory of adsorption of organic substances using the regression analysis. Comparative analysis of the data obtained was carried out.
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页码:2708 / 2716
页数:8
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