Triterpene Glycosides of Astragalus and Their Genins. LXVIII. Cycloorbigenin C, a New Cycloartane Genin

被引:0
|
作者
R. P. Mamedova
M. A. Agzamova
M. I. Isaev
机构
[1] S. Yu. Yunusov Institute of the Chemistry of Plant Substances,Academy of Sciences of the Republic of Uzbekistan
[2] S. Yu. Yunusov Institute of the Chemistry of Plant Substances,Academy of Sciences of the Republic of Uzbekistan
来源
关键词
triterpenoids; cycloartanes; cycloorbigenin C; Leguminosae; PMR and ; C NMR; J-modulation; 2D NMR: ; H-; H COSY, TOCSY, ROESY, HSQC, HMBC;
D O I
暂无
中图分类号
学科分类号
摘要
The new triterpenoid cycloartane cycloorbigenin C, the structure of which is 23ξ,24ξ-cycloartan-3β,6α,16β,23,24,25-hexaol, was obtained from the aerial part of Astragalus orbiculatus Ledeb. (Leguminosae). The structure of cycloorbigenin C was proved using chemical transformations, IR spectroscopy, electron-impact mass spectrometry, and PMR and 13C NMR spectra interpreted using J-modulation and the 2D NMR spectroscopies: 1H-1H COSY, TOCSY, ROESY, HSQC, and HMBC.
引用
收藏
页码:470 / 474
页数:4
相关论文
共 50 条
  • [41] TRITERPENE GLYCOSIDES ASTRAGALUS AND THEIR GENINS .9. CIRCULAR-DICHROISM OF CYCLOARTANE KETONES
    ISAEV, MI
    MOISEEVA, GP
    GOROVITS, MB
    ABUBAKIROV, NK
    KHIMIYA PRIRODNYKH SOEDINENII, 1986, (05): : 614 - 618
  • [42] Triterpene glycosides from Astragalus and their genins.: LXXV.: Sterols and triterpenoids from Astragalus orbiculatus
    Isaev, I. M.
    Mamedova, R. P.
    Agzamova, M. A.
    Isaev, M. I.
    CHEMISTRY OF NATURAL COMPOUNDS, 2007, 43 (03) : 358 - 359
  • [43] TRITERPENE GLYCOSIDES FROM Astragalus AND THEIR GENINS. LXXXV. STRUCTURE OF CYCLOMACROSIDE E
    Iskenderov, D. A.
    Isaev, I. M.
    Isaev, M. I.
    CHEMISTRY OF NATURAL COMPOUNDS, 2010, 46 (02) : 250 - 253
  • [44] Triterpene Glycosides of Astragalus and Their Genins. LXX. Orbicoside, the First Lanostane Glycoside from Astragalus Plants
    R. P. Mamedova
    M. A. Agzamova
    M. I. Isaev
    Chemistry of Natural Compounds, 2003, 39 : 583 - 585
  • [45] Triterpene Glycosides ofAstragalusand Their Genins. LXI. Occurrence of Cycloartane 6-O-Monodesmosides
    I. A. Sukhina
    M. A. Agzamova
    B. A. Imomnazarov
    M. I. Isaev
    Chemistry of Natural Compounds, 2000, 36 : 373 - 376
  • [46] Triterpene glycosides of Astragalus and their genins.: LXX.: Orbicoside, the first lanostane glycoside from Astragalus plants
    Mamedova, RP
    Agzamova, MA
    Isaev, MI
    CHEMISTRY OF NATURAL COMPOUNDS, 2003, 39 (06) : 583 - 585
  • [47] Cycloartane triterpene glycosides from Astragalus sieberi
    Verotta, L
    Tato, M
    El-Sebakhy, NA
    Toaima, SM
    PHYTOCHEMISTRY, 1998, 48 (08) : 1403 - 1409
  • [48] Cycloartane triterpene glycosides from Astragalus siculus
    Baratta, MT
    Ruberto, G
    PLANTA MEDICA, 1997, 63 (03) : 280 - 282
  • [49] TRITERPENE GLYCOSIDES-ASTRAGALUS AND THEIR GENINS .19. CYCLOARTANE COMPOUNDS AND STEROLS FROM ASTRAGALUS-PAMIRENSIS AND ASTRAGALUS-PTEROCEPHALUS
    AGZAMOVA, MA
    ISAEV, MI
    GOROVITS, MB
    ABUBAKIROV, NK
    KHIMIYA PRIRODNYKH SOEDINENII, 1986, (01): : 117 - 118
  • [50] Triterpene glycosides of Astragalus and their genins.: LXXII.: X-ray crystal structure of cycloorbicoside D
    Mamedova, R. P.
    Agzamova, M. A.
    Turgunov, K. K.
    Tozhiboev, A.
    Tashkhodzhaev, B.
    Isaev, M. I.
    CHEMISTRY OF NATURAL COMPOUNDS, 2006, 42 (04) : 501 - 502