Synthesis and study of hydrated uranium(VI) oxides, UO3• nH2O

被引:29
|
作者
Nipruk O.V. [1 ]
Knyazev A.V. [1 ]
Chernorukov G.N. [1 ]
Pykhova Y.P. [1 ]
机构
[1] Lobachevsky Nizhni Novgorod State University, Nizhni Novgorod 603950
关键词
hydrated uranium(VI) oxides; IR spectra; schoepite; thermal behavior;
D O I
10.1134/S1066362211020044
中图分类号
学科分类号
摘要
A procedure was developed for preparing synthetic schoepite [(UO 2)8O2(OH)12](H2O) 12 (UO3•2.25H2O). The dehydration and thermal decomposition of this compound were studied by X-ray diffraction, IR spectroscopy, and differential scanning calorimetry. The relationship between schoepite and other hydrated forms of uranium(VI) oxide was found. © 2011 Pleiades Publishing, Ltd.
引用
收藏
页码:146 / 150
页数:4
相关论文
共 50 条
  • [21] Synthesis and properties of hydrated solid solutions Hx/2V2-xMoxO5+δ • nH2O
    Zakharova, GS
    Volkov, VL
    Cherkashenko, VM
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (06) : 799 - 802
  • [22] X-Ray Photoelectron Study of Thorium Silicate ThSiO4 · nH2O and Uranium Silicate USiO4·nH2O
    Yu. A. Teterin
    I. O. Utkin
    I. V. Melnikov
    A. M. Lebedev
    A. Yu. Teterin
    K. E. Ivanov
    A. S. Nikitin
    L. Vukchevich
    Journal of Structural Chemistry, 2000, 41 : 965 - 971
  • [23] Synthesis and study of uranovanadates of the AIII(VUO6)3 • nH2O series
    Chernorukov, NG
    Suleimanov, EV
    Knyazev, AV
    Feoktistova, OV
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2000, 45 (12) : 1802 - 1808
  • [24] REACTIONS OF LIQUID SODIUM WITH TRANSITION-METAL OXIDES .3. OXIDES UO3 AND U3O8
    ADDISON, CC
    BARKER, MG
    LINTONBO.RM
    PULHAM, RJ
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (16): : 2457 - &
  • [25] REACTION OF GASEOUS BROMINE PENTAFLUORIDE WITH URANIUM COMPOUNDS .2. KINETICS OF REACTION WITH U3O8 UO2 AND UO3[1]
    JARRY, RL
    STEINDLE.MJ
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (01): : 127 - &
  • [26] Hydrated iron phosphates FePO4•nH2O and Fe4(P2O7)3•nH2O as 3 V positive electrodes in rechargeable lithium batteries
    Masquelier, C
    Reale, P
    Wurm, C
    Morcrette, M
    Dupont, L
    Larcher, D
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (08) : A1037 - A1044
  • [27] Study of Water Interaction with UO2, U2O5, and UO3: Tracking the Unexpected Reduction of Uranium Cations and Characterization of Surface-Bound Hydroxyls
    El Jamal, Ghada
    Gouder, Thomas
    Eloirdi, Rachel
    Idriss, Hicham
    Jonsson, Mats
    JOURNAL OF PHYSICAL CHEMISTRY C, 2023, 127 (29): : 14222 - 14231
  • [28] First-principles study of elastic and thermodynamic properties of UO2, γ-UO3 and α-U3O8
    Huang, Zhiyuan
    Ma, Lidong
    Zhang, Jianbao
    Zhou, Qing
    Yang, Lei
    Wang, Haifeng
    JOURNAL OF NUCLEAR MATERIALS, 2022, 572
  • [29] REACTIONS OF PULSED-LASER EVAPORATED URANIUM ATOMS WITH MOLECULAR-OXYGEN - INFRARED-SPECTRA OF UO, UO2, UO3, UO2+, UO22+, AND UO3-O2 IN SOLID ARGON
    HUNT, RD
    ANDREWS, L
    JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (05): : 3690 - 3696
  • [30] Compositions of the condensed medium and gas phase forming upon heating of uranium oxides (UO2, UO3, U3O8, and U4O9) in argon and oxygen atmosphere: Computer experiment
    Moiseev G.K.
    Shubin A.B.
    Kulikova T.V.
    Ivanovskii A.L.
    Russ. J. Inorg. Chem., 2008, 6 (913-917): : 913 - 917