Synthesis, crystal structure, and electroluminescent properties of zinc and cadmium tetradentate azomethine complexes

被引：0
|
作者：
A. S. Burlov
V. G. Vlasenko
D. A. Garnovskii
N. V. Polosareva
A. S. Antsyshkina
G. G. Sadikov
V. S. Sergienko
A. V. Churakov
Ya. V. Zubavichus
E. I. Mal’tsev
A. V. Dmitriev
D. A. Lypenko
A. S. Cheprasov
G. S. Borodkin
A. V. Metelitsa
机构：
[1] Southern Federal University,Research Institute of Physical and Organic Chemistry
[2] Southern Federal University,Research Institute of Physics
[3] Russian Academy of Sciences,Southern Scientific Center
[4] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[5] National Research Centre “Kurchatov Institute”,Frumkin Institute of Electrochemistry
[6] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2014年 / 59卷
关键词：
Organic Light Emit Diode; Coordination Shell; Complex IIIa; Local Atomic Structure; Thermal Vacuum Evaporation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Chemical and electrochemical syntheses of zinc(II) and cadmium(II) complexes based on tetradentate Schiff bases (H2L1 and H2L2) resulting from condensation of 2-tosylaminobenzaldehyde with 3,6-dioxa-1,8-octanediamine or 4,9-dioxa-1,12-dodecanediamine were performed. The structure, composition, and properties of the complexes were studied by elemental analysis, IR, 1H NMR, and UV spectroscopy, X-ray absorption spectroscopy, and X-ray diffraction. The zinc(II) and cadmium(II) complexes luminesce in a DMF solution in the blue spectral region (λPL = 425–433 nm), the photoluminescence quantum yield φ being 0.25–0.30. Multilayer zinc(II)- and cadmium(II)-based electroluminescent structures with green-blue emission of the exciplex nature were fabricated.
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页码：721 / 732
页数：11
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