Synthesis and photochromic properties of novel nonsymmetric dihetarylethenes based on benzindole and thiophene

被引：0
|
作者：
A. V. Metelitsa
V. P. Rybalkin
N. I. Makarova
P. V. Levchenko
V. S. Kozyrev
E. N. Shepelenko
L. L. Popova
V. A. Bren’
V. I. Minkina
机构：
[1] Southern Federal University,Institute of Physical and Organic Chemistry
[2] Southern Scientific Center of the Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2010年 / 59卷
关键词：
Key words; benzo[; ]indole; dihetarylethene; maleinimide; synthesis; photochromism; fluorescence; photocolorability; molecular switches.;
D O I：
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学科分类号：
摘要：
Novel nonsymmetric dihetarylethenes 3-(5-methoxy-1,2-dimethyl-1H-benzo[g]indol-3-yl)-4-(3-thienyl)-furan-2,5-dione and 1-alkyl- and 1-aryl-3-(5-methoxy-1,2-dimethyl-1H-benzo[g]indol-3-yl-4-(3-thienyl)-1(H)-pyrrole-2,5-diones were synthesized. The substitution of the furandione moiety for pyrroledione gives rise to the radiation and photochemical channels of deactivation of the electron excitation energy of dihetarylethenes. The products of photolysis of pyrrolediones undergo recyclization in both the ground and excited states.
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页码：1639 / 1644
页数：5
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