Synthesis and photochromic properties of new nonsymmetric dihetarylethenes - indole and thiophene derivatives

被引：13
|
作者：
Makarova, N. I. [1 ]
Levchenko, P. V. [1 ]
Shepelenko, E. N. [2 ]
Metelitsa, A. V. [1 ]
Kozyrev, V. S. [1 ]
Rybalkin, V. P. [2 ]
Bren, V. A. [1 ]
Minkin, V. I. [1 ,2 ]
机构：
[1] So Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, So Sci Ctr, Rostov Na Donu 344006, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 09期
关键词：
indole; thiophene; furan-2,5-dione; pyrrole-2,5-dione dihetarylethene; synthesis; photochromism; fluorescence; photocolorability; molecular switches; REVERSIBLE PHOTOCYCLIZATION; DIARYLETHENE; SYSTEMS;
D O I：
10.1007/s11172-011-0286-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New nonsymmetric dihetarylethenes were synthesized: 3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-(3-thienyl)furan-2,5-dione and photochromic 1-alkyl-(1-aryl)-3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-(3-thienyl)-1(H)-pyrrole-2,5-diones. The absence of benzoannulation in the indole moiety results in the enhancement of the efficiencies of fluorescence and photocyclization of noncyclic isomers compared to the benzoindole derivatives.
引用
收藏
页码：1899 / 1905
页数：7
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